Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Driving polymer brushes from synthesis to functioning

R Wang, Q Wei, W Sheng, B Yu, F Zhou… - Angewandte …, 2023 - Wiley Online Library
The great success of controlled radical polymerizations has encouraged researchers to
develop more facile and robust approaches for surface‐initiated polymerizations (SIPs) to …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications

J Yan, MR Bockstaller, K Matyjaszewski - Progress in Polymer Science, 2020 - Elsevier
Recent progress in surface-initiated polymerization enables the deliberate polymer
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …

Surface-Initiated Zerovalent Metal-Mediated Controlled Radical Polymerization (SI-Mt0CRP) for Brush Engineering

D Wu, W Li, T Zhang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The surface-tethered polymer brush has become a powerful approach to
tailoring the chemical and physical properties of surfaces and interfaces and revealed broad …

Design of materials with supramolecular polymers

TD Clemons, SI Stupp - Progress in Polymer Science, 2020 - Elsevier
One hundred years ago Hermann Staudinger was strongly criticized by his scientific peers
for his macromolecular hypothesis, but today it is hard to imagine a world without polymers …

Oxygen tolerance in surface-initiated reversible deactivation radical polymerizations: Are polymer brushes turning into technology?

M Fromel, EM Benetti, CW Pester - ACS Macro Letters, 2022 - ACS Publications
Over the past three decades, the development of reversible deactivation radical
polymerizations (RDRP), and advancements toward more user-friendly and accessible …

Oxygen tolerance during surface-initiated photo-ATRP: Tips and tricks for making brushes under environmental conditions

G Gazzola, I Filipucci, A Rossa… - ACS Macro …, 2023 - ACS Publications
Achieving tolerance toward oxygen during surface-initiated reversible deactivation radical
polymerization (SI-RDRP) holds the potential to translate the fabrication of polymer brush …

Oxygen tolerant and cytocompatible Iron (0)-mediated ATRP enables the controlled growth of polymer brushes from mammalian cell cultures

A Layadi, B Kessel, W Yan, M Romio… - Journal of the …, 2020 - ACS Publications
The use of zerovalent iron (Fe0)-coated plates, which act both as a source of catalyst and as
a reducing agent during surface-initiated atom transfer radical polymerization (SI-ATRP) …