Surface chemistry of porphyrins and phthalocyanines

JM Gottfried - Surface Science Reports, 2015 - Elsevier
This review covers the surface chemistry of porphyrins, phthalocyanines, their metal
complexes, and related compounds, with particular focus on chemical reactions at …

Tuning the catalytic activity of Ag (110)-supported Fe phthalocyanine in the oxygen reduction reaction

F Sedona, M Di Marino, D Forrer, A Vittadini… - Nature materials, 2012 - nature.com
A careful choice of the surface coverage of iron phthalocyanine (FePc) on Ag (110) around
the single monolayer allows us to drive with high precision both the long-range …

Reversible Change of the Spin State in a Manganese Phthalocyanine<? format?> by Coordination of CO Molecule

A Stróżecka, M Soriano, JI Pascual, JJ Palacios - Physical Review Letters, 2012 - APS
We show that the magnetic state of individual manganese phthalocyanine (MnPc) molecules
on a<? format?> Bi (110) surface is modified when the Mn 2+ center coordinates to CO …

Change of the magnetic coupling of a metal–organic complex with the substrate by a stepwise ligand reaction

BW Heinrich, G Ahmadi, VL Müller, L Braun… - Nano …, 2013 - ACS Publications
The surface-assisted intramolecular ligand reaction of a porphyrin molecule adsorbed on Au
(111) is studied by scanning tunneling microscopy and spectroscopy. The temperature …

Ferromagnetic Coupling of Mononuclear Fe Centers in a Self-Assembled<? format?> Metal-Organic Network on Au (111)

TR Umbach, M Bernien, CF Hermanns, A Krüger… - Physical Review Letters, 2012 - APS
The magnetic state and magnetic coupling of individual atoms in nanoscale structures relies
on a delicate balance between different interactions with the atomic-scale surroundings …

Interfaces between different iron phthalocyanines and Au (111): influence of the fluorination on structure and interfacial interactions

K Greulich, A Belser, T Basova, T Chasse… - The Journal of …, 2021 - ACS Publications
The interface properties of iron phthalocyanine (FePc) as well as partially fluorinated and
perfluorinated iron phthalocyanine (FePcF4 and FePcF16) have been studied and …

Scaling of Yu-Shiba-Rusinov energies in the weak-coupling Kondo regime

N Hatter, BW Heinrich, D Rolf, KJ Franke - Nature communications, 2017 - nature.com
The competition of the free-spin state of a paramagnetic impurity on a superconductor with
its screened counterpart is characterized by the energy scale of Kondo screening compared …

Nature of lone-pair–surface bonds and their scaling relations

A Kakekhani, LT Roling, A Kulkarni, AA Latimer… - Inorganic …, 2018 - ACS Publications
We investigate the (surface) bonding of a class of industrially and biologically important
molecules in which the chemically active orbital is a 2 p electron lone pair located on an N or …

Switching and sensing spin states of Co–porphyrin in bimolecular reactions on Au (111) using scanning tunneling microscopy

H Kim, YH Chang, SH Lee, YH Kim, SJ Kahng - ACS nano, 2013 - ACS Publications
Controlling and sensing spin states of magnetic molecules at the single-molecule level is
essential for spintronic molecular device applications. Here, we demonstrate that spin states …

Direct quantitative identification of the “surface trans-effect”

PS Deimel, RM Bababrik, B Wang, PJ Blowey… - Chemical …, 2016 - pubs.rsc.org
The strong parallels between coordination chemistry and adsorption on metal surfaces, with
molecules and ligands forming local bonds to individual atoms within a metal surface, have …