Transition metal-catalyzed carbonylation has emerged as a powerful and versatile strategy
for the efficient construction of complicated carbonyl-containing molecules from simple …

The iminoacylation of alkenes via photoredox N-heterocyclic carbene catalysis is developed
with the employment of alkene-tethered α-imino-oxy acids and acyl imidazoles. The …

By merging nickel-mediated facially selective aza-Heck cyclization and radical acyl C–H
activation promoted by tetrabutylammonium decatungstate (TBADT) as a hydrogen atom …

Herein, we developed a direct and effective strategy for the synthesis of sulfur-containing
carboxylic acid derivatives through copper/visible light catalyzed ring-opening carbonylation …

A photoredox‐catalyzed iminoalkenylation of γ‐alkenyl O‐acyl oximes has been developed.
Readily available alkenylboronic acids serve as alkenylation reagents, leading to densely …

The first synthesis of highly strained spirocyclobutane-pyrrolines via a palladium-catalyzed
tandem Narasaka–Heck/C (sp3 or sp2)–H activation reaction is reported here. The key step …

A novel palladium-catalyzed spirocyclization through sequential Narasaka–Heck cyclization,
C–H activation and [4+ 2] annulation has been developed. In this reaction, cheap and …

An efficient iron-catalyzed carbonylative cyclization of γ, δ-unsaturated aromatic oxime
esters with amines has been developed. A range of functionalized β-homoproline amide …

The direct iminoalkynylation of unactivated olefins with terminal alkynes is achieved for the
first time by nickel-catalyzed cascade iminyl-radical cyclization/Sonogashira-type coupling of …

O-Phenyloximes tethered to alkenes undergo 5-exo-trig iminyl radical cyclizations upon
microwave irradiation. Trapping of the resulting cyclic radicals results in C–C, C–N, C–O, C …