The allene functionality has participated in one of the most exciting voyages in organic
chemistry, from chemical curiosities to a recurring building block in modern organic …

Recent Advances and Perspectives in Transition Metal‐Catalyzed 1,4‐Functionalizations of
Unactivated 1,3‐Enynes for the Synthesis of Allenes - Fu - 2020 - Chinese Journal of Chemistry …

In contrast to the widely explored methods for the asymmetric synthesis of molecules
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …

Axial chirality widely exists in natural products, pharmaceutical compounds, and other
functional molecules; these axially chiral compounds also find wide utility as catalysts or …

Light-driven utilization of CO2 in organic synthesis is highly attractive because it mimics
nature. However, such transformations are mainly limited to the incorporation of only a …

In contrast to the wealth of asymmetric transformations for generating central chirality from
alkyl radicals, the enantiocontrol over the allenyl radicals for forging axial chirality represents …

We herein describe an asymmetric α-allylic allenylation of β-ketocarbonyls and aldehydes
with 1, 3-enynes. A synergistic chiral primary amine/Pd catalyst was identified to facilitate the …

By employing CuOAc as the catalyst, we realize a four-component reaction of 1, 3-enynes,
diselenides, DABCO·(SO2) 2, and cycloketone oxime esters, providing facile access to …

A copper-catalyzed three-component reaction of cyclobutanone oxime esters and 1, 3-
enynes in the presence of TMSCN or TMSCF3 has been developed. This mild protocol …

Chiral organophosphorous compounds are very important in catalysis, organic syntheses,
and medicinal chemistry. However, catalytic enantioselective protocols for the axially chiral …