A review of functional linear carbon chains (oligoynes, polyynes, cumulenes) and their applications as molecular wires in molecular electronics and optoelectronics

MR Bryce - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Linear, sp-hybridised, 1-dimensional (1D) all-carbon wires are conceptually the simplest π-
conjugated organic molecules. Their fundamental experimental and theoretical properties …

Pulsed laser ablation in liquid of sp-carbon chains: Status and recent advances

P Marabotti, S Peggiani, A Vidale… - Chinese Physics B, 2022 - iopscience.iop.org
This review provides a discussion of the current state of research on sp-carbon chains
synthesized by pulsed laser ablation in liquid. In recent years, pulsed laser ablation in liquid …

Syntheses, Geometric and Electronic Structures of Inorganic Cumulenes

J Tang, C Hu, AE Crumpton, M Dietz… - Journal of the …, 2024 - ACS Publications
Molecular chains of two-coordinate carbon atoms (cumulenes) have long been targeted,
due to interest in the electronic structure and applications of extended π-systems, and their …

Stable and Solution‐Processable Cumulenic sp‐Carbon Wires: A New Paradigm for Organic Electronics

S Pecorario, AD Scaccabarozzi, D Fazzi… - Advanced …, 2022 - Wiley Online Library
Abstract Solution‐processed, large‐area, and flexible electronics largely relies on the
excellent electronic properties of sp2‐hybridized carbon molecules, either in the form of π …

Stabilization of reactive sp carbon chains

P Tarakeshwar, M Meneghetti, J Wu, RL Whetten… - Carbon, 2023 - Elsevier
We describe a novel strategy for stabilizing the long-elusive, condensed-state materials
consisting of sp carbon chains. High-level ab initio calculations indicate that covalent …

Stability of the polyynic form of C 18, C 22, C 26, and C 30 nanorings: a challenge tackled by range-separated double-hybrid density functionals

E Brémond, AJ Pérez-Jiménez, C Adamo… - Physical Chemistry …, 2022 - pubs.rsc.org
We calculate the relative energy between the cumulene and polyyne structures of a set of
C4k+ 2 (k= 4–7) rings (C18, C22, C26, and C30 prompted by the recent synthesis of the …

The field-effect transistor based on a polyyne–polyene structure obtained via PVDC dehydrochlorination

OA Streletskiy, IA Zavidovskiy, IF Nuriahmetov… - Journal of Composites …, 2023 - mdpi.com
We report on the formation of the field-effect transistor based on a polyyne–polyene
structure. Polyvinylidene chloride (PVDC) drop casting and its subsequent …

[HTML][HTML] Vibrational and nonlinear optical properties of amine-capped push-pull polyynes by infrared and Raman spectroscopy

P Marabotti, A Milani, A Lucotti, L Brambilla… - Carbon Trends, 2021 - Elsevier
The vibrational properties of a series of push-pull polyynes have been studied by infrared
and Raman spectroscopy. The simultaneous activation of a strong infrared and Raman …

Disclosing Early Excited State Relaxation Events in Prototypical Linear Carbon Chains

P Kabaciński, P Marabotti, D Fazzi… - Journal of the …, 2023 - ACS Publications
One-dimensional (1D) linear nanostructures comprising sp-hybridized carbon atoms, as
derivatives of the prototypical allotrope known as carbyne, are predicted to possess …

Cumulenic sp‐Carbon Atomic Wires wrapped with Polymer for Supercapacitor Application

S Ghosh, M Righi, S Melesi, Y Qiu, RR Tykwinski… - Carbon, 2024 - Elsevier
Carbyne, the ideal linear atomic wire consisting of a single-atom thick chain of sp-carbon, is
theoretically predicted to have around five times higher surface area than graphene, notable …