Recent advances in tetra-(Ti, Sn, Zr, Hf) and pentavalent (Nb, V, Ta) metal-substituted molecular sieve catalysis

SL Suib, J Přech, E Szaniawska, J Čejka - Chemical Reviews, 2022 - ACS Publications
Metal substitution of molecular sieve systems is a major driving force in developing novel
catalytic processes to meet current demands of green chemistry concepts and to achieve …

Understanding TiO2 Photocatalysis: Mechanisms and Materials

J Schneider, M Matsuoka, M Takeuchi, J Zhang… - Chemical …, 2014 - ACS Publications
Environmental pollution and destruction as well as the lack of sufficient clean and natural
energy resources are some of the most serious problems presently faced on a global scale …

Probing zeolites by vibrational spectroscopies

S Bordiga, C Lamberti, F Bonino, A Travert… - Chemical Society …, 2015 - pubs.rsc.org
This review addresses the most relevant aspects of vibrational spectroscopies (IR, Raman
and INS) applied to zeolites and zeotype materials. Surface Brønsted and Lewis acidity and …

Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation

M Anpo, M Takeuchi - Journal of catalysis, 2003 - Elsevier
This review deals with the preparation of highly reactive titanium oxide photocatalysts and
the clarification of the active sites as well as the detection of the reaction intermediates at the …

Assignment of pre‐edge peaks in K‐edge x‐ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole?

T Yamamoto - X‐Ray Spectrometry: An International Journal, 2008 - Wiley Online Library
The characteristics of pre‐edge peaks in K‐edge x‐ray absorption near edge structure
(XANES) spectra of 3d transition metals were reviewed from viewpoints of the selection rule …

Heterogeneous catalysts obtained by grafting metallocene complexes onto mesoporous silica

T Maschmeyer, F Rey, G Sankar, JM Thomas - Nature, 1995 - nature.com
THE synthesis of mesoporous siliceous solids with large-diameter channel apertures (25–
100 Å) has greatly expanded the capabilities of heterogeneous catalysis1–7. The large …

Titania–silica as catalysts: molecular structural characteristics and physico-chemical properties

X Gao, IE Wachs - Catalysis Today, 1999 - Elsevier
Recent results on characterization and applications of titania–silica materials as
photocatalysts, acid catalysts and oxidation catalysts are reviewed. The similarities and …

Chemical and technical aspects of propene oxide production via hydrogen peroxide (HPPO process)

V Russo, R Tesser, E Santacesaria… - Industrial & …, 2013 - ACS Publications
Propene oxide is a very important chemical whose production technology has changed a lot
during the last 30 years. Nowadays, the most promising technology is the HPPO process in …

A one-step rapid synthesis of TS-1 zeolites with highly catalytically active mononuclear TiO 6 species

W Xu, T Zhang, R Bai, P Zhang, J Yu - Journal of Materials Chemistry …, 2020 - pubs.rsc.org
The modulation and determination of the coordination environments of Ti active sites in
titanosilicate zeolites are key challenges in the rational design of high-performance …