Molecular views on Fischer–Tropsch synthesis

KT Rommens, M Saeys - Chemical Reviews, 2023 - ACS Publications
For nearly a century, the Fischer–Tropsch (FT) reaction has been subject of intense debate.
Various molecular views on the active sites and on the reaction mechanism have been …

The oscillating fischer-tropsch reaction

R Zhang, Y Wang, P Gaspard, N Kruse - Science, 2023 - science.org
The mechanistic steps that underlie the formation of higher hydrocarbons in catalytic carbon
monoxide (CO) hydrogenation at atmospheric pressure over cobalt-based catalysts (Fischer …

A review of hydrogen production and storage materials for efficient integrated hydrogen energy systems

F Alasali, MI Abuashour, W Hammad… - Energy Science & …, 2024 - Wiley Online Library
The rapidly growing global need for environmentally friendly energy solutions has inspired
extensive research and development efforts aimed at harnessing the potential of hydrogen …

Revealing and Regulating the Complex Reaction Mechanism of CO2 Hydrogenation to Higher Alcohols on Multifunctional Tandem Catalysts

S Zhang, C Huang, Z Shao, H Zhou, J Chen, L Li… - ACS …, 2023 - ACS Publications
Revealing and regulating the intricate reaction mechanism of direct CO2 hydrogenation to
higher alcohols (C2+ OH), especially for the crucial C–C coupling step, is still a great …

The Impact of Support Material of Cobalt‐Based Catalysts Prepared by Double Flame Spray Pyrolysis on CO2 Methanation Dynamics

M Gäßler, J Stahl, M Schowalter, S Pokhrel… - …, 2022 - Wiley Online Library
Methanation is capable of chemical storage of fluctuating renewable energy, which requires
fundamental understanding of the dynamics of the kinetic processes taking place on the …

Microkinetic Modeling of the Transient CO2 Methanation with DFT‐Based Uncertainties in a Berty Reactor

B Kreitz, GD Wehinger, CF Goldsmith… - ChemCatChem, 2022 - Wiley Online Library
The transient operation of methanation reactors can become desirable when coupled with
fluctuating renewable energies in Power‐to‐Gas scenarios, which requires suitable kinetic …

Fischer–Tropsch Synthesis for the Production of Sustainable Aviation Fuel: Formation of Tertiary Amines from Ammonia Contaminants

RLC Voeten, F Hendriks, GL Bezemer - ACS omega, 2024 - ACS Publications
Fischer–Tropsch synthesis combined with product workup is a promising route toward
synthetic aviation fuel from renewable hydrogen and carbon sources like biomass, CO2, and …

Hydrogenation of CO/CO2 mixtures under unsteady-state conditions: Effect of the carbon oxides on the dynamic methanation process

D Meyer, J Friedland, J Schumacher, MG Gäßler… - Chemical Engineering …, 2022 - Elsevier
Abstract The Power-to-Gas (PtG) process offers the opportunity to store fluctuating
renewable energy in form of chemical energy by hydrogenating carbon oxides into methane …

[HTML][HTML] A transient flow reactor for rapid gas switching at atmospheric pressure

EA High, E Lee, C Reece - Review of Scientific Instruments, 2023 - pubs.aip.org
Herein, we present a design for a transient flow reactor system with high detection sensitivity
and minimal dead volume, such that it is capable of sub-second switching of the gas stream …

Microkinetic model validation for Fischer-Tropsch synthesis at methanation conditions based on steady state isotopic transient kinetic analysis

J Van Belleghem, J Yang, P Janssens… - Journal of Industrial and …, 2022 - Elsevier
Abstract A Single-Event MicroKinetic (SEMK) model has been extended towards the
simulation of Steady State Isotopic Transient Kinetic Analysis (SSITKA) data for Co catalyzed …