Recent developments in the difunctionalization of alkenes with C–N bond formation

X Chen, F Xiao, WM He - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
The difunctionalization of carbon–carbon double bonds, introducing two novel functional
groups onto both sides of the carbon–carbon bond in one pot, has become more and more …

An Iodine‐Catalyzed Hofmann–Löffler Reaction

C Martínez, K Muniz - Angewandte Chemie International …, 2015 - Wiley Online Library
Iodine reagents have been identified as economically and ecologically benign alternatives
to transition metals, although their application as molecular catalysts in challenging C H …

Recent Advancements on Metal‐Free Vicinal Diamination of Alkenes: Synthetic Strategies and Mechanistic Insights

R Kumar, Y Khanna, P Kaushik… - Chemistry–An Asian …, 2023 - Wiley Online Library
The oxidative aminative vicinal difunctionalization of alkenes or related chemical feedstocks
has emerged as sustainable and multipurpose strategies that can efficiently construct two …

Iodine in modern oxidation catalysis

P Finkbeiner, BJ Nachtsheim - Synthesis, 2013 - thieme-connect.com
This review discusses the origins of iodine-mediated oxidation catalysis and gives a
comprehensive overview on this young field of research. The focus is set on oxidative C–X …

Metal-Free Radical Azidoarylation of Alkenes: Rapid Access to Oxindoles by Cascade C N and C C Bond-Forming Reactions.

K Matcha, R Narayan… - Angewandte Chemie …, 2013 - search.ebscohost.com
A novel method for the oxidative radical azidation of alkenes relies on an azide in
combination with a hypervalent iodine reagent. A cascade of C N and C C bond‐forming …

Copper-catalyzed alkene aminoazidation as a rapid entry to 1, 2-diamines and installation of an azide reporter onto azahetereocycles

K Shen, Q Wang - Journal of the American Chemical Society, 2017 - ACS Publications
A copper-catalyzed aminoazidation of unactivated alkenes is achieved for the synthesis of
versatile unsymmetrical 1, 2-diamine derivatives. This transformation offers an effective …

Copper (II)/iron (III) Co-catalyzed intermolecular diamination of alkynes: facile synthesis of imidazopyridines

J Zeng, YJ Tan, ML Leow, XW Liu - Organic letters, 2012 - ACS Publications
Copper(II)/Iron(III) Co-catalyzed Intermolecular Diamination of Alkynes: Facile Synthesis of
Imidazopyridines | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log In …

Development of intramolecular vicinal diamination of alkenes: from palladium to bromine catalysis

K Muniz, C Martinez - The Journal of Organic Chemistry, 2013 - ACS Publications
Palladium catalysis has been instrumental in the development of the intramolecular
diamination of alkenes. Reagent combinations of a palladium catalyst and iodosobenzene …

[HTML][HTML] Enantioselective diamination with novel chiral hypervalent iodine catalysts

P Mizar, A Laverny, M El‐Sherbini, U Farid… - … (Weinheim an der …, 2014 - ncbi.nlm.nih.gov
Vicinal diamines constitute one the most important functional motif in organic chemistry
because of its wide occurrence in a variety of biological and pharmaceutical molecules. We …

N-Iodosuccinimide-Promoted Hofmann–Löffler Reactions of Sulfonimides under Visible Light

CQ O'Broin, P Fernández, C Martínez, K Muñiz - Organic letters, 2016 - ACS Publications
Conditions for an attractive and productive protocol for the position-selective intramolecular
C–H amination of aliphatic groups (Hofmann–Löffler reaction) are reported employing …