Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Halogen, Chalcogen, Pnictogen, and Tetrel Bonding in Non‐Covalent Organocatalysis: An Update

D Jovanovic, M Poliyodath Mohanan… - Angewandte Chemie …, 2024 - Wiley Online Library
The use of noncovalent interactions based on electrophilic halogen, chalcogen, pnictogen,
or tetrel centers in organocatalysis has gained noticeable attention. Herein, we provide an …

Managing multiple halide‐related defects for efficient and stable inorganic perovskite solar cells

Z Wang, Q Tian, H Zhang, H Xie, Y Du… - Angewandte Chemie …, 2023 - Wiley Online Library
Halide‐related surface defects on inorganic halide perovskite not only induce charge
recombination but also severely limit the long‐term stability of perovskite solar cells. Herein …

Creating organic functional materials beyond chemical bond synthesis by organic cocrystal engineering

L Sun, W Zhu, X Zhang, L Li, H Dong… - Journal of the American …, 2021 - ACS Publications
Organic cocrystal engineering refers to two or more organic molecules stoichiometrically
combined and held together by noncovalent intermolecular interactions, which differs from …

Catalysis of organic reactions through halogen bonding

RL Sutar, SM Huber - ACS Catalysis, 2019 - ACS Publications
Halogen bonding, the noncovalent interaction based on electrophilic halogen substituents,
features very interesting properties, as illustrated by numerous applications continuously …

Halogen bonding in organic synthesis and organocatalysis

D Bulfield, SM Huber - Chemistry–A European Journal, 2016 - Wiley Online Library
Halogen bonding is a noncovalent interaction similar to hydrogen bonding, which is based
on electrophilic halogen substituents. Hydrogen‐bonding‐based organocatalysis is a well …

Halogen bonding and chalcogen bonding mediated sensing

R Hein, PD Beer - Chemical Science, 2022 - pubs.rsc.org
Sigma–hole interactions, in particular halogen bonding (XB) and chalcogen bonding (ChB),
have become indispensable tools in supramolecular chemistry, with wide-ranging …

Chalcogen-bond driven molecular recognition at work

N Biot, D Bonifazi - Coordination Chemistry Reviews, 2020 - Elsevier
Out of the supramolecular toolbox, Secondary Bonding Interactions (SBIs) have attracted in
the last decades the attention of the chemical community as novel non-covalent interactions …

Computer modeling of halogen bonds and other σ-hole interactions

MH Kolar, P Hobza - Chemical reviews, 2016 - ACS Publications
In the field of noncovalent interactions a new paradigm has recently become popular. It
stems from the analysis of molecular electrostatic potentials and introduces a label, which …

Experimental binding energies in supramolecular complexes

F Biedermann, HJ Schneider - Chemical reviews, 2016 - ACS Publications
On the basis of many literature measurements, a critical overview is given on essential
noncovalent interactions in synthetic supramolecular complexes, accompanied by analyses …