Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Sulfur can form diverse S (IV) and S (VI) stereogenic centers, of which some have gained
significant attention recently due to their increasing use as pharmacophores in drug …

Historically, sulfoximines, sulfondiimines and sulfonimidamides have been neglected
pharmacophores in drug discovery even though they offer very interesting properties. This …

Achiral sulfur functional groups, such as sulfonamide, sulfone, thiol and thioether, are
common in drugs and natural products. By contrast, chiral sulfur functional groups are often …

Here we report a contractive synthesis of multisubstituted cyclobutanes containing multiple
stereocenters from readily accessible pyrrolidines using iodonitrene chemistry. Mediated by …

Sulfur is an ubiquitous heteroatom in medicinal chemistry [1]. Its prevalence is often credited
to its ability to exist in many oxidation states, whilst also being capable of bonding to a …

Sulfoximines and sulfonimidamides are promising compounds for medicinal and
agrochemistry. As monoaza analogues of sulfones and sulfonamides, respectively, they …

Thionyl tetrafluoride (SOF4) is a valuable connective gas for sulfur fluoride exchange
(SuFEx) click chemistry that enables multidimensional linkages to be created via sulfur …

Abstract We present (3+ 2)‐and (4+ 2)‐cycloadditions of donor–acceptor (D–A)
cyclopropanes and cyclobutanes with N‐sulfinylamines and a sulfur diimide, along with a …

During the last one and half decades, chemists within vastly different areas of science have
witnessed a rising interest in chemical matters incorporating the sulfonimidamide functional …