Visible-light-controlled ruthenium-catalyzed olefin metathesis
C Theunissen, MA Ashley, T Rovis - Journal of the American …, 2019 - ACS Publications
Olefin metathesis is now one of the most efficient ways to create new carbon–carbon bonds.
While most efforts focused on the development of ever-more efficient catalysts, a particular …
While most efforts focused on the development of ever-more efficient catalysts, a particular …
Ruthenium‐Catalyzed Metathesis of Conjugated Polyenes
Á Balla, M Al‐Hashimi, A Hlil, HS Bazzi… - ChemCatChem, 2016 - Wiley Online Library
In the past decade, numerous examples of chemical technologies based on olefin
metathesis have been developed to make olefin metathesis increasingly dominant in …
metathesis have been developed to make olefin metathesis increasingly dominant in …
Complete reaction pathway of ruthenium-catalyzed olefin metathesis of ethyl vinyl ether: Kinetics and mechanistic insight from DFT
Y Minenkov, G Occhipinti, VR Jensen - Organometallics, 2013 - ACS Publications
Density functional theory calculations accounting for dispersion, thermochemical, and
continuum solvent effects have been applied to study the metathesis of ethyl vinyl ether …
continuum solvent effects have been applied to study the metathesis of ethyl vinyl ether …
Retracing the evolution of monometallic ruthenium–arene catalysts for C–C bond formation
L Delaude, A Demonceau - Dalton transactions, 2012 - pubs.rsc.org
Preformed or in situ generated monometallic ruthenium–arene complexes with the generic
formula RuX2 (arene)(L)(L= phosphine or N-heterocyclic carbene) are versatile and efficient …
formula RuX2 (arene)(L)(L= phosphine or N-heterocyclic carbene) are versatile and efficient …
Synthesis of semiochemicals via olefin metathesis
Semiochemicals are substances or mixtures that carry messages and are used for
communication between individuals of the same or different species. Semiochemicals that …
communication between individuals of the same or different species. Semiochemicals that …
Phase transfer activation of fluorous analogs of grubbs' second-generation catalyst: Ring-opening metathesis polymerization
Grubbs' second-generation alkene metathesis catalyst and the fluorous analog
(H2IMes)((Rf8 (CH2) 2) 3P)(Cl) 2Ru ( CHPh)(1; H2IMes/Rf8= 1, 3-dimesityl-4, 5 …
(H2IMes)((Rf8 (CH2) 2) 3P)(Cl) 2Ru ( CHPh)(1; H2IMes/Rf8= 1, 3-dimesityl-4, 5 …
Olefin metathesis in air using latent ruthenium catalysts: imidazole substituted amphiphilic hydrogenated ROMP polymers providing nano-sized reaction spaces in …
BÖ Öztürk, B Durmuş, SK Şehitoğlu - Catalysis Science & Technology, 2018 - pubs.rsc.org
Imidazole substituted hydrogenated amphiphilic ROMP polymers were used as both
surfactants and ligand precursors for olefin metathesis reactions in water. Amphiphilic …
surfactants and ligand precursors for olefin metathesis reactions in water. Amphiphilic …
Activation of single-component nickel (II) polyethylene catalysts via phase transfer of fluorous phosphine ligands
The nickel salicylaldiminato phosphine complexes [1, 2, 3-C6H3 (9-anthracenyl) O (CH N
(2, 6-C6H3 (i Pr) 2)] Ni (Me)[P (4-C6H4R) 3](4; R= a,(CH2) 2Rf8; b,(CH2) 3Rf8; c, H …
(2, 6-C6H3 (i Pr) 2)] Ni (Me)[P (4-C6H4R) 3](4; R= a,(CH2) 2Rf8; b,(CH2) 3Rf8; c, H …
An Analogue of Grubbs Third‐Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase‐Transfer Activation of Ring‐Closing Alkene Metathesis
The title catalyst (H2IMes)[3, 5‐NC5H3 (CH2CH2Rf8) 2] 2 (Cl) 2Ru (= CHPh)[H2IMes= 1, 3‐
bis (2, 4, 6‐trimethylphenyl)‐4, 5‐dihydroimidazol‐2‐ylidene, Rf8=(CF2) 7CF3] was …
bis (2, 4, 6‐trimethylphenyl)‐4, 5‐dihydroimidazol‐2‐ylidene, Rf8=(CF2) 7CF3] was …
Azide-and Fluorine-Containing Polystyrenes as Potential ″Phosphine Sponges ″Based upon Staudinger Reactions: Application to the Phase Transfer Activation of …
K Wang, JA Gladysz - Macromolecules, 2022 - ACS Publications
There are numerous potential applications of “phosphine sponges”, but optimal systems are
yet to emerge. Toward this end, Staudinger reactions of a known polymer derived by …
yet to emerge. Toward this end, Staudinger reactions of a known polymer derived by …