Synthetic applications of oxidative aromatic coupling—from biphenols to nanographenes

M Grzybowski, B Sadowski… - Angewandte Chemie …, 2020 - Wiley Online Library
Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …

Syntheseanwendungen der oxidativen aromatischen Kupplung–von Biphenolen zu Nanographenen

M Grzybowski, B Sadowski, H Butenschön… - Angewandte …, 2020 - Wiley Online Library
Die oxidative aromatische Kupplung nimmt einen grundlegenden Platz in der modernen
Arenchemie ein. Sie ist das Mittel der Wahl für den Aufbau großer, komplizierter …

Furan‐Extended Helical Rylenes with Fjord Edge Topology and Tunable Optoelectronic Properties

T Luo, Y Wang, J Hao, PA Chen, Y Hu… - Angewandte …, 2023 - Wiley Online Library
Lateral furan‐expansion of polycyclic aromatics, which enables multiple O‐doping and
peripheral edge evolution of rylenes, is developed for the first time. Tetrafuranylperylene …

Stair-like narrow N-doped nanographene with unusual diradical character at the topological interface

Z Li, Y Tang, J Guo, J Zhang, M Deng, W Xiao, F Li… - Chem, 2023 - cell.com
The π-magnetism of finite-sized nanoribbons occurring on the topological molecular
interfaces remains largely unexplored due to limited experimental examples. Herein, we …

Bis‐peri‐dinaphtho‐rylenes: Facile Synthesis via Radical‐Mediated Coupling Reactions and their Distinctive Electronic Structures

T Shen, Y Zou, X Hou, H Wei, L Ren… - Angewandte …, 2023 - Wiley Online Library
Polycyclic aromatic hydrocarbons (PAHs) with a one‐dimensional (1D), ribbon‐like structure
have the potential to serve as both model compounds for corresponding graphene …

bay/ortho-Octa-substituted Perylene: A Versatile Building Block toward Novel Polycyclic (Hetero)Aromatic Hydrocarbons

K Yang, Z Li, Y Huang, Z Zeng - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus Polycyclic (hetero) aromatic hydrocarbons (PAHs) have emerged as a focal
point in current interdisciplinary research, spanning the realms of chemistry, physics, and …

[HTML][HTML] Synthesis, photophysical and electronic properties of tetra-donor-or acceptor-substituted ortho-perylenes displaying four reversible oxidations or reductions

J Merz, A Steffen, J Nitsch, J Fink, CB Schürger… - Chemical …, 2019 - pubs.rsc.org
Via regioselective Ir-catalyzed C–H borylation and subsequent reactions (ie, viaBr4-Per or
(BF3K) 4-Per intermediates), we have introduced strong π-donors and acceptors at the 2, 5 …

Stable Quadruple Helical Tetraradicaloid with Thermally Induced Intramolecular Magnetic Switching

J Guo, Z Li, J Zhang, B Li, Y Liang, Y Wang… - CCS …, 2022 - chinesechemsoc.org
We report an air-stable tetraradicaloid based on a rarely explored perylenequinonoid (PQ)
core, namely, tetrabenzo-annulated tetracyclopenta [b, e, k, n] perylene (TBCP), which has a …

Large aromatic hydrocarbon radical cation with global aromaticity and state-associated magnetic activity

J Guo, C Zhou, S Xie, S Luo… - Chemistry of …, 2020 - ACS Publications
The stable radical cation of large aromatic hydrocarbons remains a challenge, due to the
recessive aromatic character and high reactivity. Here we report the design, synthesis, and …

Diagonal and vertical B← N Lewis pair functionalized perylenes

Y Zhang, Z Zhang, L Ji, W Huang - Organic Letters, 2023 - ACS Publications
Two novel multiple B← N Lewis pair functionalized perylenes are reported. While OBN-Pery
shows a centrosymmetric and planar architecture, PBN-Pery displays an axisymmetric and …