[HTML][HTML] Spin state switching in iron coordination compounds

P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …

Molecular spin crossover phenomenon: recent achievements and prospects

A Bousseksou, G Molnár, L Salmon… - Chemical Society …, 2011 - pubs.rsc.org
Recently we assisted a strong renewed interest in the fascinating field of molecular spin
crossover complexes by (1) the emergence of nanosized spin crossover materials through …

Emerging properties and applications of spin crossover nanomaterials

G Molnár, L Salmon, W Nicolazzi, F Terki… - Journal of Materials …, 2014 - pubs.rsc.org
In the past few years we have witnessed the spectacular development of nano-materials of
spin crossover complexes of 3d4–3d7 transition metal ions, including thin films …

Spin transition charted in a fluorophore-tagged thermochromic dinuclear iron (II) complex

Y Garcia, F Robert, AD Naik, G Zhou… - Journal of the …, 2011 - ACS Publications
The first crystal structures of a dinuclear iron (II) complex with three N 1, N 2-1, 2, 4-triazole
bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was …

Insights into the origin of cooperative effects in the spin transition of [Fe (NH2trz) 3](NO3) 2: The role of supramolecular interactions evidenced in the crystal structure of …

MM Dirtu, C Neuhausen, AD Naik, A Rotaru… - Inorganic …, 2010 - ACS Publications
The thermally induced hysteretic spin transition (ST) that occurs in the polymeric chain
compound [Fe (NH2trz) 3](NO3) 2 (1) above room temperature (T c↑= 347 K, T c↓= 314 K) …

Influence of hydrogen bonding on the hysteresis width in iron (II) spin‐crossover complexes

B Weber, W Bauer, T Pfaffeneder, MM Dîrtu, AD Naik… - 2011 - Wiley Online Library
A detailed investigation on the properties of the high‐temperature and low‐temperature
modifications of the iron (II) spin‐crossover complex [FeL1 (HIm) 2](1) and its isotopic …

The investigation of spin-crossover systems by raman spectroscopy: a review

ZG Lada - Magnetochemistry, 2022 - mdpi.com
Spin-crossover (SCO) is a well-documented phenomenon, being intensely investigated by a
respectable number of researchers during the last decades. The conventional method for …

Spin state switching of metal complexes by visible light or hard X-rays

D Unruh, P Homenya, M Kumar, R Sindelar… - Dalton …, 2016 - pubs.rsc.org
Electromagnetic stimuli of spin crossover compounds restricted to UV-vis light irradiation for
many years could be recently extended to X-ray excitation. This review covers a large variety …

Unprecedented bistability in spin-crossover solids based on the retroaction of the high spin low-spin interface with the crystal bending

M Paez-Espejo, M Sy… - Journal of the American …, 2018 - ACS Publications
There has been in recent years a continuous increase in spatiotemporal investigations of the
dynamics of the first-order transitions in spin-crossover (SCO) solids. In single crystals, this …

Vibrational properties of the trinuclear spin crossover complex [Fe 3 (4-(2′-hydroxy-ethyl)-1, 2, 4-triazole) 6 (H 2 O) 6](CF 3 SO 3) 6: a nuclear inelastic scattering, IR …

JA Wolny, S Rackwitz, K Achterhold, Y Garcia… - Physical Chemistry …, 2010 - pubs.rsc.org
The vibrational properties of the trimeric iron complex [Fe3 (4-(2′-hydroxy-ethyl)-1, 2, 4-
triazole) 6 (H2O) 6](CF3SO3) 6 which serves as a model of the 1D iron coordination …