Comprehensive Summary Acenes with linearly fused benzene rings have attracted much
attention due to their intriguing optical and electronic properties. Nevertheless, the poor …

Despite the remarkable synthetic accomplishments in creating diverse polycyclic aromatic
hydrocarbons with B− N bonds (BN‐PAHs), their optoelectronic applications have been less …

Heterocycles containing both N and B heteroatoms in their structure were first reported by
Dewar in the middle of the last century. However, they received little attention until the early …

The development of novel organic semiconductors has continuously promoted the field of
organic optoelectronics. During the past decade, boron-and nitrogen-embedded (BN …

A two-step route to strongly absorbing and efficiently orange to deep red fluorescent, doubly
B/N-doped, ladder-type pyrrolo [3, 2-b] pyrroles has been developed. We synthesize and …

Increasing the chemical diversity of organic semiconductors is essential to develop efficient
electronic devices. In particular, the replacement of carbon‐carbon (C− C) bonds with …

The first synthesis of a tetracene BN isostere is reported. Comparison with its direct, all-
carbon analogue reveals that the BN tetracene isostere exhibits a lower-lying HOMO and a …

BN 2‐vinylnaphthalene, a BN aromatic vinyl monomer, is copolymerized with styrene under
free radical conditions. Oxidation yields styrene–vinyl alcohol (SVA) statistical copolymers …

The gram-scale polymerization of a novel azaborine vinyl monomer is reported. We describe
an efficient and high-yielding synthesis of B-vinyl-2, 1-borazanaphthalene. Homopolymers …

The isoelectronic replacement of CC bonds with− BN+ bonds in polycyclic aromatic
hydrocarbons (PAHs) is a widely used tool to prepare novel optoelectronic materials. Far …