NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions

YG Gorbunova, AG Martynov, KP Birin… - Russian Journal of …, 2021 - Springer
Coordination compounds of lanthanides attract increasing attention of researchers due to
their unique physical and chemical properties, including interesting optical and magnetic …

Synthetic approaches to lanthanide complexes with tetrapyrrole type ligands

VE Pushkarev, LG Tomilova… - Russian Chemical …, 2008 - iopscience.iop.org
Approaches to the synthesis of single-, double-and triple-decker complexes of lanthanides
with phthalocyanines and their analogues known to date are considered. Examples of …

Redox-Triggered Switching of Conformational State in Triple-Decker Lanthanide Phthalocyaninates

AG Martynov, MA Polovkova, YG Gorbunova… - Molecules, 2022 - mdpi.com
Double-and triple-decker lanthanide phthalocyaninates exhibit unique physical-chemical
properties, particularly single-molecule magnetism. Among other factors, the magnetic …

Novel near-IR absorbing phenyl-substituted phthalo-and naphthalocyanine complexes of lanthanide (III): synthesis and spectral and electrochemical properties

TV Dubinina, KV Paramonova, SA Trashin… - Dalton …, 2014 - pubs.rsc.org
A series of novel phenyl-substituted planar and sandwich-type complexes of Eu, Er and Lu
with phthalo and naphthalocyanine ligands was obtained. A successful synthesis of …

Heteroleptic Crown-Substituted Tris (phthalocyaninates) as Dynamic Supramolecular Scaffolds with Switchable Rotational States and Tunable Magnetic Properties

AG Martynov, MA Polovkova, GS Berezhnoy… - Inorganic …, 2021 - ACS Publications
Herein we report single-crystal X-ray diffraction characterization and complementary
solution studies of supramolecular interaction between potassium salts and heteroleptic …

Determination of the structural parameters of heteronuclear (phthalocyaninato) bis (crownphthalocyaninato) lanthanide (III) triple-deckers in solution by simultaneous …

MA Polovkova, AG Martynov, KP Birin… - Inorganic …, 2016 - ACS Publications
Application of a general and convenient approach to the synthesis of heteronuclear crown-
substituted triple-decker phthalocyaninates afforded two series of complexes containing one …

Orientation-induced redox isomerism in planar supramolecular systems

SL Selektor, AV Shokurov, VV Arslanov… - The Journal of …, 2014 - ACS Publications
In this work, a previously undescribed phenomenon of orientation-induced redox isomerism
in a Langmuir monolayer is revealed in the case of cerium bis-[tetra-(15-crown-5) …

New insights into sensors based on radical bisphthalocyanines

ML Rodriguez-Méndez, M Gay… - Journal of Porphyrins and …, 2009 - World Scientific
The unique semiconducting, optical and electrochemical properties of radical lanthanide
bisphthalocyanines make them ideal materials for sensing applications. A variety of …

Crown-substituted phthalocyanines—components of molecular ionoelectronic materials and devices

AG Martynov, YG Gorbunova, AY Tsivadze - Russian Journal of Inorganic …, 2014 - Springer
This review summarizes the synthetic approaches towards oxa-crown-substituted
phthalocyanines (CRPc's) including various metal complexes of s-, p-, d-, and f-elements …

Impact of the coordination environment on the magnetic properties of single-molecule magnets based on homo-and hetero-dinuclear terbium (III) heteroleptic tris …

RJ Holmberg, MA Polovkova, AG Martynov… - Dalton …, 2016 - pubs.rsc.org
A series of TbIII triple-decker heteroleptic crownphthalocyaninate complexes consisting of a
homodinuclear compound [(15C5) 4Pc] Tb [(15C5) 4Pc] Tb (Pc)(1), and two novel …