Transition metal–catalyzed C─ H bond activation and borylation is a powerful synthetic
method that offers versatile synthetic transformation from organoboron compounds to …

Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …

Transition metal‐catalyzed enantioselective C− H activation of prochiral sulfoximines for non‐
annulated products remains a formidable challenge. We herein report iridium‐catalyzed …

Transition metal‐catalyzed site‐and stereoselective C− H activation of strained (hetero)
cycloalkanes remains a formidable challenge. We herein report a carbamate‐directed …

Reported here is an efficient and simple ether‐directed iridium‐catalyzed enantioselective C
(sp3)− H borylation of cyclopropanes. Various functional groups were well‐tolerated …

Comprehensive Summary We herein report a simple ether‐directed iridium‐catalyzed site‐
and enantioselective C (sp2)‐H borylation of benzhydryl ethers for the first time. Various …

Axially chiral compounds with a rotation restricted N− C bond are of great importance in
synthetic chemistry, pharmaceuticals, and material sciences. The search for efficient and …

Organosilicon compounds are highly important molecular scaffolds with versatile synthetic
utility, and are used in a range of transformations. Such organosilicon compounds are …

Organoborons play a crucial role in organic synthesis, easing the construction of C–C and C–
X bonds which in turn sensitize C–H borylation reactions. In the consideration of inert C …

Silyl-phenanthroline (NN′ Si) ligand ancillary iridium-catalyzed C (sp3)–H borylation is
investigated theoretically. Density functional theory calculations clearly disclose that the …