Cationic Phosphinidene as a Versatile P1 Building Block:[LC–P]+ Transfer from Phosphonio–Phosphanides [LC–P–PR3]+ and Subsequent LC Replacement …
P Royla, K Schwedtmann, Z Han… - Journal of the …, 2023 - ACS Publications
Cationic imidazoliumyl (phosphonio)-phosphanides [LC–P–PR3]+(1a–e+, LC= 4, 5-dimethyl-
1, 3-diisopropylimidazolium-2-yl; R= alkyl, aryl) are obtained via the nucleophilic …
1, 3-diisopropylimidazolium-2-yl; R= alkyl, aryl) are obtained via the nucleophilic …
Probing Radical Addition to 1‐Phosphabutadienes by Employing Muonium as a “Light Isotope” of Hydrogen
HTG Walsgrove, PW Percival… - Chemistry–A European …, 2024 - Wiley Online Library
Understanding free radical addition to multiple bonds is important to elucidating the
mechanistic details of addition polymerization reactions, albeit the fleeting radical …
mechanistic details of addition polymerization reactions, albeit the fleeting radical …
B-substituted group 1 phosphides: synthesis and reactivity
M Aman, L Dostál, A Růžička, Z Růžičková… - Dalton …, 2023 - pubs.rsc.org
1-Boryl-8-phosphinonaphthalenes 1-BCy2-8-PCl2-C10H6 (1) and 1-BCy2-8-PPhCl-C10H6
(2) were prepared and used as starting materials for the synthesis of B-substituted …
(2) were prepared and used as starting materials for the synthesis of B-substituted …
Non‐Ionic Peterson‐type Olefination Reactivity and its Use in a Silicon‐promoted Carbonyl‐Carbonyl Cross Coupling Reaction
T Thi Tran, A Arkhypchuk, S Ott - Angewandte Chemie - Wiley Online Library
The [2+ 2] cycloaddition reaction between the Si= C double bond of adamantylsilene and
the carbonyl group of aliphatic, aromatic or acetylenic ketones and aldehydes is …
the carbonyl group of aliphatic, aromatic or acetylenic ketones and aldehydes is …
Phosphaalkene Metathesis to Tetraaryl Olefins
D Zhao, J Han - Synfacts, 2023 - thieme-connect.com
Significance: Reductive couplings of carbonyl compounds to alkenes typically involve
radical or polar mechanisms and are commonly less competent with bulky structures. In this …
radical or polar mechanisms and are commonly less competent with bulky structures. In this …