Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds

P Shieh, MR Hill, W Zhang, SL Kristufek… - Chemical …, 2021 - ACS Publications
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …

[HTML][HTML] Heteroatom-containing degradable polymers by ring-opening metathesis polymerization

J Xu, N Hadjichristidis - Progress in Polymer Science, 2023 - Elsevier
The incorporation of heteroatom-containing weak bonds along polymer backbones has
become a popular tool to accelerate degradation. Many methods have already been …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Main-chain poly (phosphoester) s: History, syntheses, degradation, bio-and flame-retardant applications

KN Bauer, HT Tee, MM Velencoso, FR Wurm - Progress in Polymer …, 2017 - Elsevier
Nature on planet earth is dominated by poly (phosphoester) s (PPEs). They structure and
determine life in the form of deoxy-and ribonucleic acid (DNA & RNA), and, as …

Olefin metathesis polymerization: Some recent developments in the precise polymerizations for synthesis of advanced materials (by ROMP, ADMET)

Y Chen, MM Abdellatif, K Nomura - Tetrahedron, 2018 - Elsevier
Recent results for synthesis of end-functionalized polymers (EFP) by using olefin metathesis
polymerization have been introduced including basic characteristics in ring-opening …

Post‐Functionalization of Polymers via Orthogonal Ligation Chemistry

AS Goldmann, M Glassner, AJ Inglis… - Chemistry of Organo …, 2014 - Wiley Online Library
This chapter highlights the current status of critically selected post‐functionalization
techniques of polymers via orthogonal ligation chemistry, reports the major characteristics of …

Established and emerging strategies for polymer chain‐end modification

DJ Lunn, EH Discekici, J Read de Alaniz… - Journal of Polymer …, 2017 - Wiley Online Library
The development of “controlled” and “living” polymerization processes with high end‐group
fidelity has enabled an unprecedented range of polymeric materials with specific chain‐end …

Degradable polyphosphoramidate via ring-opening metathesis polymerization

Y Liang, H Sun, W Cao, MP Thompson… - ACS macro …, 2020 - ACS Publications
We report the synthesis of a degradable polyphosphoramidate via ring-opening metathesis
polymerization (ROMP) with the Grubbs initiator (IMesH2)(C5H5N) 2 (Cl) 2Ru═ CHPh …

Hyperbranched poly (phosphoester) s as flame retardants for technical and high performance polymers

K Täuber, F Marsico, FR Wurm, B Schartel - Polymer chemistry, 2014 - pubs.rsc.org
A structurally novel hyperbranched halogen-free poly (phosphoester)(hbPPE) is proposed
as a flame retardant in poly (ester) s and epoxy resins. hb polymeric flame retardants …

A general decomposition pathway for phosphine-stabilized metathesis catalysts: Lewis donors accelerate methylidene abstraction

WL McClennan, SA Rufh, JAM Lummiss… - Journal of the …, 2016 - ACS Publications
Sterically accessible Lewis donors are shown to accelerate decomposition during catalysis,
for a broad range of Grubbs-class metathesis catalysts. These include benzylidene …