[HTML][HTML] A perspective on PEF synthesis, properties, and end-life

K Loos, R Zhang, I Pereira, B Agostinho, H Hu… - Frontiers in …, 2020 - frontiersin.org
This critical review considers the extensive research and development dedicated, in the last
years, to a single polymer, the poly (ethylene 2, 5-furandicarboxylate), usually simply …

[HTML][HTML] Tuning the properties of furandicarboxylic acid-based polyesters with copolymerization: A review

Z Terzopoulou, L Papadopoulos, A Zamboulis… - Polymers, 2020 - mdpi.com
Polyesters based on 2, 5-furandicarboxylic acid (FDCA) are a new class of biobased
polymers with enormous interest, both from a scientific and industrial perspective. The …

Inside PEF: Chain conformation and dynamics in crystalline and amorphous domains

CF Araujo, MM Nolasco, PJA Ribeiro-Claro… - …, 2018 - ACS Publications
A thorough vibrational spectroscopy and molecular modeling study on poly (ethylene 2, 5-
furandicarboxylate)(PEF) explores its conformational preferences, in the amorphous and …

Poly (butylene 2, 4-furanoate), an added member to the class of smart furan-based polyesters for sustainable packaging: Structural isomerism as a key to tune the final …

E Bianchi, M Soccio, V Siracusa… - ACS sustainable …, 2021 - ACS Publications
High-molecular-weight poly (butylene 2, 4-furanoate)(2, 4-PBF), an isomer of well-known
poly (butylene 2, 5-furanoate)(2, 5-PBF), was synthesized through an eco-friendly solvent …

Chain Conformation, Molecular Dynamics, and Thermal Properties of Poly(n-methylene 2,5-furanoates) as a Function of Methylene Unit Sequence Length

G Papamokos, T Dimitriadis, DN Bikiaris… - …, 2019 - ACS Publications
Poly (n-methylene 2, 5-furanoates) is a family of biobased polymers with outstanding gas
barrier and mechanical properties and with the potential to frame the future in certain …

Bio-based and one-day compostable poly (diethylene 2, 5-furanoate) for sustainable flexible food packaging: Effect of ether-oxygen atom insertion on the final …

S Quattrosoldi, G Guidotti, M Soccio, V Siracusa, N Lotti - Chemosphere, 2022 - Elsevier
In the present work, the effect of ether oxygen atom introduction in a furan ring-containing
polymer has been evaluated. Solvent-free polycondensation process permitted the …

Renewable Furfural-Based Polyesters Bearing Sulfur-Bridged Difuran Moieties with High Oxygen Barrier Properties

AM Ahmed, TP Kainulainen, JA Sirviö… - …, 2022 - ACS Publications
With the goal of achieving high barrier with bio-based materials, for example, for packaging
applications, a series of novel furfural-based polyesters bearing sulfide-bridged difuran …

Microstructural consequences of isothermal crystallization in homo-and co-polyesters based on 2, 5-and 2, 4-furandicarboxylic acid

A Bourdet, C Fosse, MR Garda, S Thiyagarajan… - Polymer, 2023 - Elsevier
Different position isomers of furandicarboxylic acid (FDCA) can be obtained from the
biomass by a Henkel disproportionation reaction. 2, 5-and 2, 4-FDCA are obtained in …

[HTML][HTML] Inter and intra molecular dynamics in poly (trimethylene 2, 5-furanoate) as revealed by infrared and Broadband Dielectric Spectroscopies

O Gálvez, O Toledano, FJ Hermoso, A Linares, M Sanz… - Polymer, 2023 - Elsevier
Infrared spectroscopy (IR) and Broadband Dielectric Spectroscopy (BDS) experiments have
been performed in poly (trimethylene 2, 5-furanoate)(PTF) and poly (trimethylene …

Green polymeric materials: On the dynamic homogeneity and miscibility of furan-based polyester blends

N Poulopoulou, A Pipertzis, N Kasmi, DN Bikiaris… - Polymer, 2019 - Elsevier
Abstract Polyesters from 2, 5-furandicarboxylic acid are considered as biobased alternatives
to their terephthalate counterparts. This work is focused on polymer blends comprised of …