Recent advances in the chemistry of bicyclo-and 1-azabicyclo [1.1. 0] butanes

A Fawcett - Pure and Applied Chemistry, 2020 - degruyter.com
Abstract Bicyclo [1.1. 0]-and 1-azabicyclo [1.1. 0] butanes are structurally unique compounds
that exhibit diverse chemistry. Bicyclo [1.1. 0] butane is a four-membered carbocycle with a …

Ring-opening, cycloaddition and rearrangement reactions of nitrogen-substituted cyclopropane derivatives

VA Rassadin, Y Six - Tetrahedron, 2016 - Elsevier
Nitrogen-substituted cyclopropane compounds encompass a range of molecules with very
diverse chemical properties: aminocyclopropanes, N-cyclopropyl amides …

Hydrogenation of solid hydrogen cyanide HCN and methanimine CH2NH at low temperature

P Theulé, F Borget, F Mispelaer, G Danger… - Astronomy & …, 2011 - aanda.org
Context. Hydrogenation reactions dominate grain surface chemistry in dense molecular
clouds and lead to the formation of complex saturated molecules in the interstellar medium …

The renaissance of strained 1-azabicyclo [1.1. 0] butanes as useful reagents for the synthesis of functionalized azetidines

M Andresini, L Degennaro, R Luisi - Organic & Biomolecular …, 2020 - pubs.rsc.org
Since their discovery in the late 1960s, 1-azabicyclo [1.1. 0] butanes have demonstrated to
be interesting precursors of azetidines, because of the peculiar reactivity of the C3–N bond …

Experimental investigation of aminoacetonitrile formation through the Strecker synthesis in astrophysical-like conditions: reactivity of methanimine (CH2NH), ammonia …

G Danger, F Borget, M Chomat, F Duvernay… - Astronomy & …, 2011 - aanda.org
Context. Studing chemical reactivity in astrophysical environments is an important means for
improving our understanding of the origin of the organic matter in molecular clouds, in …

Alternative solvents for life: framework for evaluation, current status, and future research

W Bains, JJ Petkowski, S Seager - Astrobiology, 2024 - liebertpub.com
Life is a complex, dynamic chemical system that requires a dense fluid solvent in which to
take place. A common assumption is that the most likely solvent for life is liquid water, and …

Preparation, characterization, and synthetic potential of unstable compounds containing phosphorus-carbon multiple bonds

AC Gaumont, JM Denis - Chemical reviews, 1994 - ACS Publications
One of the most important results in the field of phosphorus chemistry from the 1970s is
probably the development of the chemistry of trivalent phosphorus derivatives bearing px-px …

Synthesis of Azepine Derivatives by Rhodium‐Catalyzed Tandem 2, 3‐Rearrangement/Heterocyclization

I Nakamura, M Okamoto, Y Sato, M Terada - Angewandte Chemie, 2012 - infona.pl
Ein einfacher Weg zu N‐Heterocyclen: Die effiziente Synthese von Azepinderivaten gelingt
durch eine Rh‐katalysierte Tandem‐2, 3‐Umlagerung, die mit einer Heterocyclisierung von …

The mechanism of hexamethylenetetramine (HMT) formation in the solid state at low temperature

V Vinogradoff, A Rimola, F Duvernay… - Physical Chemistry …, 2012 - pubs.rsc.org
There is convincing evidence that the formation of complex organic molecules occurred in a
variety of environments. One possible scenario highlights the universe as a giant reactor for …

Submillimeter wave spectroscopy and astronomical search for 1-propanimine

L Margulès, A Remijan, A Belloche… - Astronomy & …, 2022 - aanda.org
Context. Methanimine, CH 2 NH, and ethanimine, CH 3 CHNH, were both detected in the
interstellar medium (ISM), the former in the 1970s and the latter nearly a decade ago. By …