Abstract The XCF 3 groups (X= O, S, Se) play an increasingly important role in modern
organic chemistry due to their unique electronegativity, lipophilic nature, metabolic stability …

Direct fluoroalkoxylation reactions of (hetero) arenes, carbon‐carbon multiple bonds, and
substitution reactions at Csp3 carbon centers by CF3O, CHF2O, and (CF3) 2CFO groups are …

Herein, we report a method for C3-selective C–H tri-and difluoromethylthiolation of
pyridines. The method relies on borane-catalyzed pyridine hydroboration for generation of …

A novel and efficient strategy for trifluoromethylthiolation and dearomatization of activated
alkynes with stable and readily available AgSCF3 has been developed. Reported herein is …

Due to the strong electron‐withdrawing nature and high lipophilicity of trifluoromethoxy
group (OCF3), methods for introducing OCF3 into organic molecules are in high demand …

The only known method for the dearomative trifluoromethoxylation of indoles is preliminary,
with only one substrate successfully undergoing the reaction. In this study, we not only …

The redox potential gap between arylsulfonium salts and [Me4N][SeCF3] has been clearly
revealed by CV measurements. Construction of the carbon–selenium bond by overcoming …

Abstract Phase Transfer Catalysis (PTC) is a powerful tool to perform reactions in a practical
fashion, both in laboratory and industrial scale. Significant cost savings and major process …

Polyfluoroaryl compounds belong to privileged moieties and engender distinct properties in
many pharmaceuticals, agrochemicals, and materials. Over the past decade, considerable …

A catalyst‐and additive‐free decarbonylative trifluoromethylthiolation of aldehyde feedstocks
has been developed. This operationally simple, scalable, and open‐to‐air transformation is …