Challenges on molecular aspects of dealumination and desilication of zeolites

MC Silaghi, C Chizallet, P Raybaud - Microporous and Mesoporous …, 2014 - Elsevier
Zeolites are widely used heterogeneous catalysts in the field of chemistry and refining.
These microporous and crystalline aluminosilicates exhibit a strong Brønsted acidity making …

Zeolites and related materials as catalyst supports for hydrocarbon oxidation reactions

A Martins, N Nunes, AP Carvalho, LM Martins - Catalysts, 2022 - mdpi.com
Catalytic oxidation is a key technology for the conversion of petroleum-based feedstocks into
useful chemicals (eg, adipic acid, caprolactam, glycols, acrylates, and vinyl acetate) since …

Siting and distribution of framework aluminium atoms in silicon-rich zeolites and impact on catalysis

J Dědeček, Z Sobalík, B Wichterlová - Catalysis Reviews, 2012 - Taylor & Francis
Siting of Al atoms in the framework T sites, in zeolite rings and channel/cavity system, and
the distribution of Al atoms between single Al atoms and close Al atoms in various Al-O-(Si …

Zeolitic materials with hierarchical porous structures

S Lopez‐Orozco, A Inayat, A Schwab… - Advanced …, 2011 - Wiley Online Library
During the past several years, different kinds of hierarchical structured zeolitic materials
have been synthesized due to their highly attractive properties, such as superior mass/heat …

Full compositional flexibility in the preparation of mesoporous MFI zeolites by desilication

D Verboekend, S Mitchell, M Milina… - The Journal of …, 2011 - ACS Publications
We demonstrate that desilication in alkaline medium is a suitable post-synthetic method to
introduce intracrystalline mesoporosity in MFI zeolites independent of the Si/Al ratio in the …

Synthesis of mesoporous ZSM-5 zeolites through desilication and re-assembly processes

WC Yoo, X Zhang, M Tsapatsis, A Stein - Microporous and Mesoporous …, 2012 - Elsevier
ZSM-5 zeolite crystals with secondary mesopores were synthesized by alkaline desilication
and surfactant-induced re-assembly of dissolved species (ie, silicates, aluminosilicates and …

Tuning high-density polyethylene hydrocracking through mordenite zeolite crystal engineering

PA Kots, PA Doika, BC Vance, S Najmi… - ACS Sustainable …, 2023 - ACS Publications
We investigate the hydrocracking of high-density polyethylene using a bifunctional Pt/Al2O3
and modified mordenite acid catalyst. Mass transport limitations impact polymer diffusion …

Effect of Enhanced Accessibility of Acid Sites in Micromesoporous Mordenite Zeolites on Hydroisomerization of n-Hexane

J Pastvova, D Kaucky, J Moravkova, J Rathousky… - Acs …, 2017 - ACS Publications
This paper describes a study of the nature and the accessibility of the acid sites in
micromesoporous mordenite zeolites obtained by desilication and dealumination and …

How defects and crystal morphology control the effects of desilication

S Svelle, L Sommer, K Barbera, PNR Vennestrøm… - Catalysis today, 2011 - Elsevier
The introduction of mesoporosity in zeolites by desilication has become a simple routine
method to generate hierarchical materials with improved catalytic performance. The …

Sustainable upgrade of bioderived glycerol to solketal through acetalization over metal-free mordenite catalysts

B Saini, AP Tathod, SK Saxena… - ACS Sustainable …, 2022 - ACS Publications
In the current work, acetalization of crude glycerol to produce valuable solketal, a renewable
fuel additive, is studied over metal-free mordenite-based catalysts. The perfect combination …