This article intends to highlight and comprehensively summarize the recent developments in
the field of silylene–coinage metal chemistry. Recent years have witnessed exponential …

The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic
ligand toward transition metals. The strong silylene–metal binding related to both increased …

Gold catalysis has emerged as an important tool in the field of synthetic organic chemistry for
the selective functionalization of C–C multiple bonds. The research in India on gold catalysis …

Cationic Au (I) complexes (2, 5 and 8) supported by N-heterocyclic carbene, silylene and
germylene ligands were prepared and their potential as catalysts in glycosidation chemistry …

This work describes the synthesis and coordination behavior of a new mixed‐donor ligand
PhC (NtBu) 2SiC6H4PPh2 (1) containing both silylene and phosphine donor sites. Ligand 1 …

We have prepared two new silylene–phosphine-based hybrid ligands Si {N (R) C6H4
(PPh2)}{PhC (N t Bu) 2}[R= TMS {trimethylsilyl}(1) and TBDMS {tert-butyldimethylsilyl}(2)] …

This work presents the different coordination nature of the bidentate ligand towards gold and
silver complexes. The reaction of 1 with AuClSMe2 in dichloromethane resulted in two gold …

A platinum (0) complex bearing a cyclic (alkyl)(amino) silylene and a 1, 3-divinyl-1, 1, 3, 3-
tetramethyldisiloxane (DVTMS) was synthesized and isolated in the form of colorless …

Herein for the first time we report monocoordinated cationic Cu (I) complexes with
unsymmetrical arenes (toluene and m-xylene)[LCu (η3-C7H8)]+[SbF6]− and [{LCu (η2 …

A convenient new method was added to the toolbox of the ligand design of N-heterocyclic
silylenes and their transition-metal complexes. Herein we report on six novel compounds of …