Unnatural amino acids are important scaffolds for novel drug candidates, and especially α‐
alkyl amino acids have emerged as a valuable variant. This is due to the ubiquity of alkyl …

Vinyl sulfones are important structural motifs with a wide range of applications in the
biomedical field. Although the hydrosulfonylations of alkynes have provided straightforward …

A general electrochemical system for reductive hydrodefunctionalization is described,
employing the inexpensive and easily available triethylamine (Et3N) as a sacrificial …

Low‐valent Ti‐mediated homolytic C− O bond cleavage offers unified access to carbon
radicals from ubiquitous non‐activated tertiary, secondary, and even primary alcohols. In …

Hydrodehalogenation is a straightforward approach for detoxifications of harmful
anthropogenic organohalide‐based pollutants, as well as removal of halide protecting …

The carbon–carbon bond formation via autoxidation of organoboronic acid using 1 atm of
O2 is achieved in a simple, clean, and green fashion. The approach allows a technically …

Post-translational modifications (PTMs) greatly expand the structures and functions of
proteins in nature,. Although synthetic protein functionalization strategies allow mimicry of …

A simple protocol for hydrodebromination and‐deiodination of halo (hetero) arenes was
enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies …

A visible-light-induced chemoselective reactions of quinoxalin-2 (1 H)-ones with
alkylboronic acids in the presence of air (O 2) and N 2 atmosphere was developed under …

A direct and site-specific alkylation of (sp3) C–H bond with aliphatic boronic acid was
achieved. By simply heating glycinates and amines together with alkylboronic acids under …