The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

Enantioselective Silver-Catalyzed Transformations | Chemical Reviews ACS ACS Publications
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We report herein the first examples of catalytic enantioselective synthesis of axially chiral 3‐
arylpyrroles. Reaction of α‐isocyanoacetates with β‐aryl‐α, β‐alkynic ketones in the …

Developing an efficient and reliable catalytic protocol to access atropisomeric compounds,
especially those bearing five-membered heteroaryl structures with lower rotation barriers, is …

We disclose a Ag-catalyzed asymmetric interrupted Barton–Zard reaction of α-aryl-
substituted isocyanoacetates with 2-and 3-nitroindoles, which enables the dearomatization …

The cyclization of allenoates with activated isocyanides was reported for the first time. While
Ag catalysis led to an unprecedented enantioselective synthesis of 3 H pyrroles, a simple …

Catalytic asymmetric dynamic kinetic resolution of configurationally labile bridged biaryls is
emerging as a powerful strategy for atropisomer synthesis. However, the reported examples …

Herein we report a catalytic asymmetric dearomatization reaction of electron‐deficient
heteroarenes with α‐substituted isocyanoacetates through an interrupted Barton–Zard …

α-Imino esters are useful precursors for the synthesis of a variety of types of natural and
unnatural α-amino acid derivatives, with a wide range of biological activities. Due to the …

The development of catalytic enantioselective isocyanide‐based reactions is currently of
great interest because the resulting products are valuable in organic synthesis …