Exploring hydroperoxides in combustion: History, recent advances and perspectives
The aim of this paper is to review recent progress in detection and quantification of
hydroperoxides, and to understand their reaction kinetics in combustion environments …
hydroperoxides, and to understand their reaction kinetics in combustion environments …
Chemical kinetics of cyclic ethers in combustion
LS Tran, O Herbinet, HH Carstensen… - Progress in Energy and …, 2022 - Elsevier
Abstract Cyclic Ethers (CEs) belong to a class of compounds of importance to understand
the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of …
the chemistry of both the engine auto-ignition of hydrocarbon fuels and the combustion of …
Elucidation of radical-and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons
Understanding hydrocarbon generation in the zeolite-catalysed conversions of methanol
and methyl chloride requires advanced spectroscopic approaches to distinguish the …
and methyl chloride requires advanced spectroscopic approaches to distinguish the …
Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis
Unveiling catalytic mechanisms at a molecular level aids rational catalyst design and
selectivity control for process optimization. In this study, we find that the Brønsted acid site …
selectivity control for process optimization. In this study, we find that the Brønsted acid site …
Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …
Isomer-dependent catalytic pyrolysis mechanism of the lignin model compounds catechol, resorcinol and hydroquinone
The catalytic pyrolysis mechanism of the initial lignin depolymerization products will help us
develop biomass valorization strategies. How does isomerism influence reactivity, product …
develop biomass valorization strategies. How does isomerism influence reactivity, product …
Continuous pyrolysis microreactors: Hot sources with little cooling? New insights utilizing cation velocity map imaging and threshold photoelectron spectroscopy
Resistively heated silicon carbide microreactors are widely applied as continuous sources to
selectively prepare elusive and reactive intermediates with astrochemical, catalytic, or …
selectively prepare elusive and reactive intermediates with astrochemical, catalytic, or …
New analytical tools for advanced mechanistic studies in catalysis: photoionization and photoelectron photoion coincidence spectroscopy
P Hemberger, JA van Bokhoven… - Catalysis Science & …, 2020 - pubs.rsc.org
What are the reaction mechanisms responsible for the selective product formation in
catalysis? How can we identify the reactive intermediates steering the reaction towards the …
catalysis? How can we identify the reactive intermediates steering the reaction towards the …
Five-membered ring compounds from the ortho-benzyne + methyl radical reaction under interstellar conditions
J Bouwman, MN McCabe, CN Shingledecker… - Nature …, 2023 - nature.com
Reactive open-shell species, such as radicals and biradicals, are key intermediates in the
formation of (poly) cyclic hydrocarbon species in a variety of interstellar environments …
formation of (poly) cyclic hydrocarbon species in a variety of interstellar environments …
Photoion Mass-Selected Threshold Photoelectron Spectroscopy to Detect Reactive Intermediates in Catalysis: From Instrumentation and Examples to Peculiarities …
Photoion mass-selected threshold photoelectron spectroscopy (ms-TPES) is a synchrotron-
based, universal, sensitive, and multiplexed detection tool applied in the areas of catalysis …
based, universal, sensitive, and multiplexed detection tool applied in the areas of catalysis …