The halogen bond

G Cavallo, P Metrangolo, R Milani, T Pilati… - Chemical …, 2016 - ACS Publications
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …

Principles and Applications of CF2X Moieties as Unconventional Halogen Bond Donors in Medicinal Chemistry, Chemical Biology, and Drug Discovery

S Vaas, MO Zimmermann, D Schollmeyer… - Journal of Medicinal …, 2023 - ACS Publications
As an orthogonal principle to the established (hetero) aryl halides, we herein highlight the
usefulness of CF2X (X= Cl, Br, or I) moieties. Using tool compounds bearing CF2X moieties …

Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

Exploiting the mechanical bond effect for enhanced molecular recognition and sensing

JT Wilmore, PD Beer - Advanced Materials, 2024 - Wiley Online Library
The ubiquity of charged species in biological and industrial processes has resulted in ever‐
increasing interest in their selective recognition, detection, and environmental remediation …

Supramolecular hierarchy among halogen and hydrogen bond donors in light-induced surface patterning

M Saccone, V Dichiarante, A Forni… - Journal of Materials …, 2015 - pubs.rsc.org
Halogen bonding, a noncovalent interaction possessing several unique features compared
to the more familiar hydrogen bonding, is emerging as a powerful tool in functional materials …

Recent advances in the chemistry of 1, 2, 4-oxadiazoles

A Pace, S Buscemi, AP Piccionello, I Pibiri - Advances in Heterocyclic …, 2015 - Elsevier
Oxadiazoles experienced an almost 80-year long period of scientific lethargy before they
tickled the curiosity of chemists. The study of chemical and photochemical reactivity of 1, 2, 4 …

Stabilizing volatile liquid chemicals using co-crystallization

CB Aakeröy, TK Wijethunga, J Benton… - Chemical …, 2015 - pubs.rsc.org
A convenient, effective, and scalable protocol for stabilizing volatile liquid chemicals is
reported. Through the use of halogen-bond driven co-crystal synthesis, several examples of …

Comparison of isomeric meta-and para-diiodotetrafluorobenzene as halogen bond donors in crystal engineering

N Bedeković, V Stilinović, T Friščić, D Cinčić - New journal of chemistry, 2018 - pubs.rsc.org
We provide a systematic investigation of the structures and composition of halogen-bonded
cocrystals involving the bent (meta) halogen bond donor 1, 3-diiodotetrafluorobenzene (1, 3 …

Fusion of materials with directional-selection and family-selection properties to prepare covalent organic framework composite with superior selective adsorption …

Y Zou, L Wang, Q Liu, Y Yang, D Wang, Y Tao… - Separation and …, 2024 - Elsevier
Materials with high adsorption properties and high selectivity are ideal adsorbents for the
application of adsorption. Herein, by using tetrabrombisphenol A (TBr-BPA) as the template …

Interlocked supramolecular polymers created by combination of halogen-and hydrogen-bonding interactions through anion-template self-assembly

F Zapata, L Gonzalez, A Caballero… - Journal of the …, 2018 - ACS Publications
We present the synthesis and oxoanion-assembling properties of a monomer with a
naphthalene ring as a central core decorated with two arms containing iodotriazolium rings …