Epoxidation processes by pyridoxal dioxomolybdenum (VI)(Pre) catalysts without organic solvent
Molybdenum (VI) pyridoxal thiosemicarbazonato complexes have proved to be efficient
catalysts in the olefinic epoxidation of cyclooctene by aqueous TBHP in the absence of an …
catalysts in the olefinic epoxidation of cyclooctene by aqueous TBHP in the absence of an …
Molybdenum compounds in organic synthesis
RI Khusnutdinov, TM Oshnyakova… - Russian Chemical …, 2017 - iopscience.iop.org
The review presents the first analysis and systematic discussion of data published in the last
35–40 years on the use of molybdenum compounds and complexes in organic synthesis …
35–40 years on the use of molybdenum compounds and complexes in organic synthesis …
Catalytic olefin epoxidation with η5-cyclopentadienyl molybdenum complexes
N Grover, FE Kuhn - Current Organic Chemistry, 2012 - ingentaconnect.com
Applications of η5-cyclopentadienyl molybdenum complexes as catalysts for achiral and
chiral epoxidation of olefins are reviewed. The discussion is categorized according to the …
chiral epoxidation of olefins are reviewed. The discussion is categorized according to the …
An Octanuclear Molybdenum(VI) Complex Containing Coordinatively Bound 4,4′-di-tert-Butyl-2,2′-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis …
TR Amarante, P Neves, C Tome, M Abrantes… - Inorganic …, 2012 - ACS Publications
The reaction of [MoO2Cl2 (di-t Bu-bipy)](1)(di-t Bu-bipy= 4, 4′-di-tert-butyl-2, 2′-
bipyridine) with water at 100–120° C in a Teflon-lined stainless steel autoclave, in an open …
bipyridine) with water at 100–120° C in a Teflon-lined stainless steel autoclave, in an open …
Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl–pyridylimine complexes as catalyst precursors
AC Gomes, SM Bruno, S Gago, RP Lopes… - Journal of …, 2011 - Elsevier
The ligand N-(n-propyl)-2-pyridylmethanimine (pyim) and an immobilised analogue of this
ligand (MCM-41-pyim) were prepared by the condensation reaction of 2 …
ligand (MCM-41-pyim) were prepared by the condensation reaction of 2 …
Dioxomolybdenum (VI) complexes containing chiral oxazolines applied in alkenes epoxidation in ionic liquids: A highly diastereoselective catalyst
JA Brito, S Ladeira, E Teuma, B Royo… - Applied Catalysis A …, 2011 - Elsevier
New monometallic dioxomolybdenum complexes, 2 and 3, containing the bis (oxazoline) B
and the oxazolinyl-pyridine C respectively, have been prepared and fully characterized both …
and the oxazolinyl-pyridine C respectively, have been prepared and fully characterized both …
Molybdenum (II) diiodo-tricarbonyl complexes containing nitrogen donor ligands as catalyst precursors for the epoxidation of methyl oleate
CA Gamelas, P Neves, AC Gomes, AA Valente… - Catalysis letters, 2012 - Springer
The molybdenum (II) tricarbonyl complexes [Mo (CO) 3 I 2 L n](n= 1, L= 2, 2′-bipyridine, 4,
4′-di-tert-butyl-2, 2′-bipyridine; n= 2, L= pyridine, 4-tert-butylpyridine) have been …
4′-di-tert-butyl-2, 2′-bipyridine; n= 2, L= pyridine, 4-tert-butylpyridine) have been …
Molybdenum versus Tungsten for the Epoxidation of Cyclooctene Catalyzed by [Cp*2M2O5]
P Sözen‐Aktaş, E Manoury… - European Journal of …, 2013 - Wiley Online Library
The catalytic activity of [Cp* 2M2O5](M= Mo, W; Cp*= pentamethylcyclopentadienyl) for the
homogeneous epoxidation of a solution of cyclooctene in MeCN/toluene follows the order …
homogeneous epoxidation of a solution of cyclooctene in MeCN/toluene follows the order …
Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide
P Neves, TR Amarante, AC Gomes, AC Coelho… - Applied Catalysis A …, 2011 - Elsevier
The tetracarbonyl complexes cis-[Mo (CO) 4 {2-[3 (5)-pyrazolyl] pyridine}](1) and cis-[Mo
(CO) 4 {ethyl [3-(2-pyridyl)-1-pyrazolyl] acetate}](2) were obtained in excellent yields by …
(CO) 4 {ethyl [3-(2-pyridyl)-1-pyrazolyl] acetate}](2) were obtained in excellent yields by …
Bis (pyrazolyl) methanetetracarbonyl-molybdenum (0) as precursor to a molybdenum (VI) catalyst for olefin epoxidation
S Figueiredo, AC Gomes, JA Fernandes… - Journal of …, 2013 - Elsevier
Bis (pyrazolyl) methanetetracarbonyl-molybdenum (0), cis-[Mo (CO) 4 (BPM)](1), was
prepared from Mo (CO) 6 and the ligand bis (pyrazolyl) methane (BPM), and examined as a …
prepared from Mo (CO) 6 and the ligand bis (pyrazolyl) methane (BPM), and examined as a …