The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …

The electrocatalytic N2 reduction reaction (NRR) offers an alternative to the traditional Haber–
Bosch (H–B) process for the synthesis of ammonia (NH3) and has received a surge of …

New electrochemical ammonia (NH3) synthesis technologies are of interest as a
complementary route to the Haber–Bosch process for distributed fertilizer generation, and …

The activation of dinitrogen by coordination to transition metal ions is a widely used and
promising approach to the utilization of Earth's most abundant nitrogen source for chemical …

The electrification of ammonia synthesis is a key target for its decentralization and lowering
impact on atmospheric CO2 concentrations. The lithium metal electrochemical reduction of …

Electrocatalytic nitrogen reduction (N2R) mediated by well-defined molecular catalysts is
poorly developed by comparison with other reductive electrocatalytic transformations …

Molecular catalysts capable of performing electrochemical transformations are frequently
utilized in the synthesis of fuels. A common benchmark for evaluating catalysts for …

Terminal and bridging end-on coordination of N2 to transition metal complexes offer
possibilities for distinct pathways in ammonia synthesis and N2 functionalization. Here we …

Electrocatalysis is a promising technology for clean energy conversion. The prediction of
activation energies is essential for reliably modeling electrocatalytic processes. Currently, a …

This review describes recent progress in N 2 activation and transformation by molecular
multimetallic polyhydride complexes. The hydride ligands can serve as electron and proton …