Experimental observations and data from quantum chemical calculations on complexes
between water molecules and small, oxygen‐containing inorganic species that play an …

The available data on main group (Groups 12–18) Lewis acid–base, donor–acceptor,
charge-transfer and van der Waals complexes stabilised by matrix isolation techniques are …

Apparent large deviations of water solutions from ideal behavior are eliminated by taking
account of the number of water molecules binding to solute sufficiently strongly (13.0±1.5 …

The FTIR spectra of the silica xerogel–H2O2 composite, obtained by the sol–gel technique,
were examined. To support interpretation of the experimental data, vibrational frequencies …

Transient absorption spectra and decay profiles of HO2 have been measured using cw near-
IR two-tone frequency modulation absorption spectroscopy at 297 K and 50 Torr in diluent of …

The stability of various alkoxy/aryloxy/peroxy radicals, as well as TEMPO and triplet
dioxygen (3O2) has been explored at a variety of theoretical levels. Good correlations …

The matrix isolation technique was initially introduced for spectroscopic investigations of
reactive species, and infrared spectra of numerous free radicals trapped in noble gas …

Carbonyl oxide is a well-known intermediate formed in gas-phase reactions of ozone with
alkenes. Secondary reactions of carbonyl oxide are suggested to lead to the formation of …

Infrared spectra from 25 to 4000 cm-1 have been recorded of water (H2O, D2O and H218O)
matrix isolated in neon, argon, and krypton matrices. Intermolecular absorption bands of …

Hydroperoxides are formed in significant amounts in the atmosphere by oxidation of volatile
organic compounds and are key in aerosol formation. In a room-temperature experiment, we …