Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

J Dupont, BC Leal, P Lozano, AL Monteiro… - Chemical …, 2024 - ACS Publications
Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …

[HTML][HTML] Rhodium-catalyzed hydroformylation under green conditions: Aqueous/organic biphasic,“on water”, solventless and Rh nanoparticle based systems

W Alsalahi, AM Trzeciak - Coordination Chemistry Reviews, 2021 - Elsevier
Hydrofomylation is an important industrial process for aldehyde production which follows the
atom-economy principle. In this homogeneous process, the separation and subsequent …

Kinetics of 1-dodecene hydroformylation in a thermomorphic solvent system using a rhodium-biphephos catalyst

G Kiedorf, DM Hoang, A Müller, A Jörke… - Chemical Engineering …, 2014 - Elsevier
The hydroformylation of 1-dodecene on a rhodium-biphephos catalyst complex exploiting a
thermomorphic multicomponent solvent system was studied experimentally in a batch …

Adjacent MnOx clusters enhance the hydroformylation activity of rhodium single-atom catalysts

Y Zheng, Q Yang, S Wang, S Furukawa, M Li… - Applied Catalysis B …, 2024 - Elsevier
Hydroformylation reactions promoted by Rh single-atom catalysts typically exhibit a negative
reaction order for CO and a positive reaction order for H 2 and alkenes. To enhance the …

Hydroformylation of 1‐dodecene with water‐soluble rhodium catalysts with bidentate ligands in multiphase systems

T Hamerla, A Rost, Y Kasaka, R Schomäcker - ChemCatChem, 2013 - Wiley Online Library
A hydrophilic metal–ligand complex formed from the precursor [dicarbonyl (acetylacetonato)
rhodium (I)]{[Rh (acac)(CO) 2]} and the bidentate ligand [2, 7‐bis (SO3Na)‐4, 5‐bis …

Model-based identification and experimental validation of the optimal reaction route for the hydroformylation of 1-dodecene

B Hentschel, G Kiedorf, M Gerlach… - Industrial & …, 2015 - ACS Publications
Previously developed kinetic and dynamic models of the hydroformylation of 1-dodecene in
a thermomorphic multicomponent solvent system (TMS), consisting of DMF, n-decane, and …

Rh (I) complexes supported on a biopolymer as recyclable and selective hydroformylation catalysts

BCE Makhubela, A Jardine, GS Smith - Green chemistry, 2012 - pubs.rsc.org
Chitosan-supported Rh complexes were prepared in a stable form to form new catalysts and
have been characterized using elemental analysis, UV-vis, FT-IR, ICP-MS, PXRD, solid state …

Rhodium-catalyzed hydroformylation of long-chain olefins in aqueous multiphase systems in a continuously operated miniplant

T Pogrzeba, D Müller, T Hamerla… - Industrial & …, 2015 - ACS Publications
We investigate aqueous multiphase systems for catalytic gas/liquid reactions, namely, the
rhodium-catalyzed hydroformylation of the long-chain olefin 1-dodecene. The multiphase …

Hydroformylation and tandem isomerization–hydroformylation of n-decenes using a rhodium-BiPhePhos catalyst: Kinetic modeling, reaction network analysis and …

A Jörke, T Gaide, A Behr, A Vorholt… - Chemical Engineering …, 2017 - Elsevier
The rhodium-BiPhePhos catalyzed hydroformylation of n-decenes, as representative long-
chain olefins, was investigated in this study experimentally and theoretically. Besides …

Analysis of the reaction network for the Rh-catalyzed hydroformylation of 1-dodecene in a thermomorphic multicomponent solvent system

J Markert, Y Brunsch, T Munkelt, G Kiedorf… - Applied Catalysis A …, 2013 - Elsevier
The hydroformylation of 1-dodecene was studied using Rh (acac)(CO) 2 and a ligand as a
catalyst in a thermomorphic multicomponent solvent (TMS) system consisting of N, N …