The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

The merger of transition metal catalysis and photocatalysis, termed metallaphotocatalysis,
has recently emerged as a versatile platform for the development of new, highly enabling …

The oxidative addition of aryl halides to bipyridine-or phenanthroline-ligated nickel (I) is a
commonly proposed step in nickel catalysis. However, there is a scarcity of complexes of this …

Transition-metal-catalysed cross-coupling reactions have become one of the most used
carbon–carbon and carbon–heteroatom bond-forming reactions in chemical synthesis …

The recent success of nickel catalysts in stereoconvergent cross-coupling and cross-
electrophile coupling reactions partly stems from the ability of monovalent nickel species to …

Photoredox nickel catalysis has emerged as a powerful strategy for cross-coupling
reactions. Although the involvement of paramagnetic Ni (I)/Ni (III) species as active …

Heteroatom-containing motifs are one of the most privileged scaffolds for pharmaceuticals,
agrochemicals, and functional materials. Transition-metal-catalyzed carbon–heteroatom …

Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

Herein we describe the synthesis of a family of aryl-Co (III)-carboxylate complexes and their
reactivity with ethyl diazoacetate. Crystallographic, full spectroscopic characterization, and …

We describe a unified nickel platform for the perfluoroalkylation of heteroarenes and
peptides. Catalysis proceeds at room temperature without using photosensitizers. The …