Organophosphorus compounds in organic electronics

MA Shameem, A Orthaber - Chemistry–A European Journal, 2016 - Wiley Online Library
This Minireview describes recent advances of organophosphorus compounds as opto‐
electronic materials in the field of organic electronics. The progress of (hetero‐) phospholes …

Quantum-chemical insights into mixed-valence systems: within and beyond the Robin–Day scheme

M Parthey, M Kaupp - Chemical Society Reviews, 2014 - pubs.rsc.org
In mixed-valence (MV) systems essentially identical, more or less electronically coupled,
redox centres are brought into formally different oxidation states by removal or addition of an …

(Multi) ferrocenyl five-membered heterocycles: excellent connecting units for electron transfer studies

A Hildebrandt, H Lang - Organometallics, 2013 - ACS Publications
The electro-and spectroelectrochemical behavior of diverse (multi) ferrocenyl five-
membered heterocyclic compounds, including furan, thiophene, pyrroles, phospholes, etc. is …

Electronic coupling in 1, 2, 3-triazole bridged ferrocenes and its impact on reactive oxygen species generation and deleterious activity in cancer cells

P Biegański, E Kovalski, N Israel, E Dmitrieva… - Inorganic …, 2022 - ACS Publications
Mixed-valence (MV) binuclear ferrocenyl compounds have long been studied as models for
testing theories of electron transfer and in attempts to design molecular-scale electronic …

Pentasubstituted Phospholes with extended π-conjugated Arm–Synthesis, electrochemistry, spectra and quantum chemical calculations

L Koláčná, P Polák, A Liška, T Tobrman, J Ludvík - Electrochimica Acta, 2023 - Elsevier
Abstract λ 3–1H-Phosphole is a unique heterocyclic compound characterized by low
aromaticity with a limited number of cross-coupling reactions to allow side-chain …

Ferrocenyl-based di-and trinuclear lanthanide complexes: solid state structures,(spectro) electrochemical and DFT studies

A Khalladi, E Kovalski, MA Abdulmalic, T Rüffer… - Dalton …, 2023 - pubs.rsc.org
Dinuclear and trinuclear ferrocenylcarboxylato-bridged lanthanide complexes of type [Ln
(μO: κ2OO′-O2CFc)(O2CFc) 2 (H2O)(dmf)] 2·(dmf) 2 (Ln= Sm (2), Eu (3), Gd (4), Tb (5); Fc …

Key multi (ferrocenyl) complexes in the interplay between electronic coupling and electrostatic interaction

S Santi, A Bisello, R Cardena, A Donoli - Dalton Transactions, 2015 - pubs.rsc.org
In this review, the properties of the most significant examples of multi (ferrocenyl) cations
containing a number of ferrocenyl units from two to six are discussed and the results are …

Substituent influence on charge transfer interactions in α, α′-diferrocenylthiophenes

JM Speck, M Korb, T Rüffer, A Hildebrandt… - …, 2014 - ACS Publications
Within a series of α, α′-diferrocenylthiophenes, the influence of electron-withdrawing
substituents at the ferrocenyl moieties and electron-donating functionalities at the thiophene …

Synthesis, characterization, electrochemistry, and computational studies of ferrocenyl-substituted siloles

SW Lehrich, A Hildebrandt, T Rüffer, M Korb… - …, 2014 - ACS Publications
Ferrocenylsiloles of the type 2, 5-Fc2-3, 4-Ph2-c C4SiR2 (3a, R= Me; 3b, R= Ph) have been
prepared by reductive cyclization from diethynylsilanes, followed by ferrocenylation using …

Influence of P‐Bonded Bulky Substituents on Electronic Interactions in Ferrocenyl‐Substituted Phospholes

D Miesel, A Hildebrandt, M Korb… - … A European Journal, 2015 - Wiley Online Library
Diferrocenyl‐1‐Ar‐1H‐phospholes 3 a–e (Ar= phenyl (a), ferrocenyl (b), mesityl (c), 2, 4, 6‐
triphenylphenyl (d), and 2, 4, 6‐tri‐tert‐butylphenyl (e)) have been prepared by reactions of …