Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Catalytic methodologies that enable the synthesis of complex organic molecules from simple
and readily available starting materials represent a goal in modern synthetic chemistry. In …

Stereochemically defined tetrasubstituted olefins are widespread structural elements of
organic molecules and key intermediates in organic synthesis. However, flexible methods …

Single metal/multiligand catalysis (SMMLC) has recently been developed for the highly
efficient and selective synthesis of valuable compounds. As a newly emerged member of …

We describe a dual strategy in Cu catalysis based on an unprecedented dynamic
multiligand coordination pool that triggers cooperative polar/radical pathways in a single …

A Cu/Pd-catalyzed borylative coupling of allenes with allyl carbonates is reported.
Synergistic Cu/Pd catalysis enables a divergent selectivity compared to Cu catalysis and …

Silver salts are one of the most widely used additives in Pd-catalysed transformations. Apart
from acting as a halide scavenger and/or an external oxidant, over the past decade it has …

Unlike the comprehensive development of tandem multi‐metallic catalysis, bimetallic
synergistic catalysis has been challenging to achieve high stereoselectivity with the …

Organoboron compounds, especially alkenylboronates and arylboronates are highly useful
reagents and versatile building blocks in the modern synthetic chemistry toolbox. This …