How softness matters in soft nanogels and nanogel assemblies

A Scotti, MF Schulte, CG Lopez, JJ Crassous… - Chemical …, 2022 - ACS Publications
Softness plays a key role in determining the macroscopic properties of colloidal systems,
from synthetic nanogels to biological macromolecules, from viruses to star polymers …

Microgels react to force: mechanical properties, syntheses, and force-activated functions

MF Schulte, E Izak-Nau, S Braun, A Pich… - Chemical Society …, 2022 - pubs.rsc.org
Microgels are colloidal polymer networks with high molar mass and properties between rigid
particles, flexible macromolecules, and micellar aggregates. Their unique stimuli …

Thermochromic-based bimodal sensor for strain-insensitive temperature sensing and synchronous strain sensing

F Xie, F Lu, Y Tian, X Zhang, Y Wang, L Zheng… - Chemical Engineering …, 2023 - Elsevier
High-sensitivity flexible sensors have broad applications, but their cross-sensitivity to
temperature variations and deformations often results in unwanted signal interference …

Environment-dependent single-chain mechanics of synthetic polymers and biomacromolecules by atomic force microscopy-based single-molecule force spectroscopy …

Y Bao, Z Luo, S Cui - Chemical Society Reviews, 2020 - pubs.rsc.org
“The Tao begets the One. One begets all things of the world.” This quote from Tao Te Ching
is still inspiring for scientists in chemistry and materials science: The “One” can refer to a …

Physics in ordered and disordered colloidal matter composed of poly (N-isopropylacrylamide) microgel particles

PJ Yunker, K Chen, MD Gratale, MA Lohr… - Reports on Progress …, 2014 - iopscience.iop.org
This review collects and describes experiments that employ colloidal suspensions to probe
physics in ordered and disordered solids and related complex fluids. The unifying feature of …

Resolving the different bulk moduli within individual soft nanogels using small-angle neutron scattering

JE Houston, L Fruhner, A de la Cotte… - Science …, 2022 - science.org
The bulk modulus, K, quantifies the elastic response of an object to an isotropic
compression. For soft compressible colloids, knowing K is essential to accurately predict the …

Does Flory–Rehner theory quantitatively describe the swelling of thermoresponsive microgels?

CG Lopez, W Richtering - Soft Matter, 2017 - pubs.rsc.org
The swelling of thermoresponsive microgels is widely modelled through Flory–Rehner
theory, which combines Flory–Huggins solution thermodynamics with the affine network …

The role of ions in the self-healing behavior of soft particle suspensions

A Scotti, U Gasser, ES Herman… - Proceedings of the …, 2016 - National Acad Sciences
Impurities in crystals generally cause point defects and can even suppress crystallization.
This general rule, however, does not apply to colloidal crystals formed by soft microgel …

Buckling and Interfacial Deformation of Fluorescent Poly(N-isopropylacrylamide) Microgel Capsules

F Hagemans, F Camerin, N Hazra, J Lammertz, F Dux… - ACS …, 2023 - ACS Publications
Hollow microgels are fascinating model systems at the crossover between polymer vesicles,
emulsions, and colloids as they deform, interpenetrate, and eventually shrink at higher …

Fragility and strength in nanoparticle glasses

P Van Der Scheer, T Van De Laar, J Van Der Gucht… - ACS …, 2017 - ACS Publications
Glasses formed from nano-and microparticles form a fascinating testing ground to explore
and understand the origins of vitrification. For atomic and molecular glasses, a wide range of …