Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

The interesting and diverse biological activities of nitrogen-containing compounds make the
construction of the C–N bond of great importance. Despite the tremendous advances that …

Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

A method for the regiodivergent aminooxygenation of aryl olefins under electrophotocatalytic
conditions is described. The procedure employs a trisaminocyclopropenium (TAC) ion …

N–N linkages are found in many natural compounds and endow fascinating structural and
functional properties. In comparison to the myriad methods for the construction of C–N …

Over the years, alkaloids derived from indole dearomatization, such as indolenine and
indolines have been evolved as promising therapeutic agents due to their important …

Reported herein is a new iron‐catalyzed diastereoselective olefin diazidation reaction which
occurs at room temperature (1–5 mol% of catalysts and dr values of up to> 20: 1). This …

Electrophilic aminating reagents have seen a renaissance in recent years as effective
nitrogen sources for the synthesis of unprotected amino functionalities. Based on their …

Herein, we study the mechanism of iron-catalyzed direct synthesis of unprotected
aminoethers from olefins by a hydroxyl amine derived reagent using a wide range of …

Recent advances in nitrene chemistry from acyclic precursors are reviewed in this paper.
Early developments in nitrene chemistry predominantly focused on exploiting new nitrene …