Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

[HTML][HTML] Pillararene/Calixarene-based systems for battery and supercapacitor applications

S Cao, H Zhang, Y Zhao, Y Zhao - EScience, 2021 - Elsevier
Pillararene/calixarene-based functional materials have garnered significant attention for
their unique topological/chemical structures and physicochemical properties, and their …

Atomic design of carbon-based dual-metal site catalysts for energy applications

H Shang, D Liu - Nano Research, 2023 - Springer
Carbon-based dual-metal sites catalysts (DMSCs) have emerged as a new frontier in the
field of sustainable energy due to their unique coordination environments, electronic …

Electrostatic stabilization of single-atom catalysts by ionic liquids

S Ding, Y Guo, MJ Hülsey, B Zhang, H Asakura, L Liu… - Chem, 2019 - cell.com
In single-atom catalysts (SACs), the isolated metal atoms on solid support are often charged.
Taking advantage of this common feature, we establish ionic liquid-stabilized single-atom …

Supported metal pair-site catalysts

E Guan, J Ciston, SR Bare, RC Runnebaum… - ACS …, 2020 - ACS Publications
Complexes with neighboring metal centers in isolated pairs and their analogues on surfaces
are drawing increasing attention as catalysts. These include molecular homogeneous …

Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO 2

F Doherty, H Wang, M Yang… - Catalysis Science & …, 2020 - pubs.rsc.org
In this Minireview, we discuss recent advances in understanding nanocluster and single-
atom catalysts for CO and CO2 emissions control applications. Through analyzing …

Metallocalix [n] arenes in catalysis: A 13-year update

O Santoro, C Redshaw - Coordination Chemistry Reviews, 2021 - Elsevier
Aside from their applications in the fields of ion extraction, gas storage and molecular
sensors, calixarenes have been extensively employed as ligands for metal complexation …

Recent advances in single-atom catalysts and single-atom alloys: opportunities for exploring the uncharted phase space in-between

ECH Sykes, P Christopher - Current Opinion in Chemical Engineering, 2020 - Elsevier
Single-atom catalysts (SACs) have gained significant world-wide attention for exhibiting
distinct reactivity and selectivity for important reactions, while utilizing precious metals at the …

Resolving the structure of the E 1 state of Mo nitrogenase through Mo and Fe K-edge EXAFS and QM/MM calculations

C Van Stappen, AT Thorhallsson, L Decamps… - Chemical …, 2019 - pubs.rsc.org
Biological nitrogen fixation is predominately accomplished through Mo nitrogenase, which
utilizes a complex MoFe7S9C catalytic cluster to reduce N2 to NH3. This cluster requires the …