Comproportionation and disproportionation in nickel and copper complexes

CS Day, R Martin - Chemical Society Reviews, 2023 - pubs.rsc.org
Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

A unified approach to decarboxylative halogenation of (hetero) aryl carboxylic acids

TQ Chen, PS Pedersen, NW Dow… - Journal of the …, 2022 - ACS Publications
Aryl halides are a fundamental motif in synthetic chemistry, playing a critical role in metal-
mediated cross-coupling reactions and serving as important scaffolds in drug discovery …

Bidentate, monoanionic auxiliary-directed functionalization of carbon–hydrogen bonds

O Daugulis, J Roane, LD Tran - Accounts of chemical research, 2015 - ACS Publications
Conspectus In recent years, carbon–hydrogen bond functionalization has evolved from an
organometallic curiosity to a tool used in mainstream applications in the synthesis of …

Copper-catalyzed C–H functionalization reactions: efficient synthesis of heterocycles

XX Guo, DW Gu, Z Wu, W Zhang - Chemical reviews, 2015 - ACS Publications
Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles |
Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical …

Copper-catalyzed electrochemical C–H amination of arenes with secondary amines

QL Yang, XY Wang, JY Lu, LP Zhang… - Journal of the …, 2018 - ACS Publications
Electrochemical oxidation represents an environmentally friendly solution to conventional
methods that require caustic stoichiometric chemical oxidants. However, C–H …

Aerobic copper-catalyzed organic reactions

SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations

R Trammell, K Rajabimoghadam… - Chemical …, 2019 - ACS Publications
Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …

Copper-catalyzed aerobic oxidations of organic molecules: pathways for two-electron oxidation with a four-electron oxidant and a one-electron redox-active catalyst

SD McCann, SS Stahl - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Selective oxidation reactions have extraordinary value in organic chemistry,
ranging from the conversion of petrochemical feedstocks into industrial chemicals and …

Copper‐Catalyzed Aerobic Oxidative C H Functionalizations: Trends and Mechanistic Insights

AE Wendlandt, AM Suess… - Angewandte Chemie …, 2011 - Wiley Online Library
The selective oxidation of C H bonds and the use of O2 as a stoichiometric oxidant
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …