Thiol–ene (click) reactions as efficient tools for terpene modification

M Firdaus - Asian Journal of Organic Chemistry, 2017 - Wiley Online Library
Abstract This Focus Review highlights the application of thiol–ene (click) chemistry to the
production of a diverse range of materials that are derived from terpenes. To present an …

Preparation of new biobased coatings from a triglycidyl eugenol derivative through thiol-epoxy click reaction

D Guzman, X Ramis, X Fernandez-Francos… - Progress in Organic …, 2018 - Elsevier
A new triglycidyl eugenol derivative (3EPO-EU) was synthesized and characterized by
spectroscopic techniques, and used as starting monomer in the preparation of novel bio …

[HTML][HTML] Preparation and characterization of a series of self-healable bio-based poly (thiourethane) vitrimer-like materials

F Guerrero, X Ramis, S De la Flor, À Serra - Polymers, 2023 - mdpi.com
A series of poly (thiourethanes)(PTUs) from biobased monomers have been synthesized.
Limonene and squalene were transformed into polyfunctional thiols by thiol-ene reaction …

New bio-based materials obtained by thiol-ene/thiol-epoxy dual curing click procedures from eugenol derivates

D Guzman, X Ramis, X Fernández-Francos… - European Polymer …, 2017 - Elsevier
Novel bio-based and dual-curable thermosets were prepared from eugenol derivatives. The
curing sequence combined two click reactions, a photoinduced radical thiol-ene reaction …

Fully renewable thermosets based on bis-eugenol prepared by thiol-click chemistry

D Guzman, A Serra, X Ramis… - Reactive and Functional …, 2019 - Elsevier
Thiol-ene photocuring and thiol-epoxy thermal curing have been applied to prepare new
thermosets from renewable substrates. As monomers, a tetrallyl and a tetraepoxy derivative …

[HTML][HTML] Enhancement in the glass transition temperature in latent thiol-epoxy click cured thermosets

D Guzmán, X Ramis, X Fernández-Francos, A Serra - Polymers, 2015 - mdpi.com
Tri and tetrafunctional thiol were used as curing agent for diglycidyl ether of bisphenol A
(DGEBA) catalyzed by a commercially available amine precursor, LC-80. Triglycidyl …

[HTML][HTML] Bio-based crosslinked polymers synthesized from functionalized soybean oil and squalene by thiol–ene UV curing

S Grauzeliene, D Valaityte, G Motiekaityte… - Materials, 2021 - mdpi.com
The development of polymers photopolymerized from renewable resources are extensively
growing as fulfills green chemistry and green engineering principles. With the rapid growth …

Novel thermal curing of cycloaliphatic resins by thiol–epoxy click process with several multifunctional thiols

D Guzmán, B Mateu, X Fernández‐Francos… - Polymer …, 2017 - Wiley Online Library
Novel thermosets were prepared by the base‐catalysed reaction between a cycloaliphatic
resin (ECC) and various thiol crosslinkers. 4‐(N, N‐Dimethylaminopyridine)(DMAP) was …

[HTML][HTML] Effect of selected thiols on cross-linking of acrylated epoxidized soybean oil and properties of resulting polymers

S Kasetaite, S De la Flor, A Serra, J Ostrauskaite - Polymers, 2018 - mdpi.com
The effect of the chemical structure and functionality of three structurally different thiols on
the cross-linking of acrylated epoxidized soybean oil and on the properties of the resulting …

Closed-Loop Recycling and Upcycling of Fully Biobased Poly (thiourethane) Covalent Adaptable Networks

S Lee, J Lyu, A Jeong, M Jung, JH Kang… - ACS Sustainable …, 2024 - ACS Publications
Thermosetting polymers have been widely used in a variety of industrial applications due to
their improved mechanical robustness, chemical inertness, and thermal stability. However …