Chiral amines are key structural motifs present in a wide variety of natural products, drugs,
and other biologically active compounds. During the past decade, significant advances have …

This review classifies and summarizes the past 10–15 years of advancements in the field of
metal-involving (ie, metal-mediated and metal-catalyzed) reactions of oximes. These …

Chiral hydroxylamines are vital substances in bioscience and versatile subunits in the
preparation of a variety of functional molecules. However, asymmetric and non-asymmetric …

This Review recaps the achievements in the field of metal-catalyzed asymmetric direct
hydrogenation of nonactivated and activated imines. A summary of the reported catalytic …

Due to their low reactivity, difficult enantiocontrol, and proneness to N–O bond cleavage, the
catalytic asymmetric hydrogenation of oximes to hydroxylamines has remained a significant …

Abstract Owing to their distinctive 1, 3‐dipolar structure, the catalytic asymmetric
hydrogenation of nitrones to hydroxylamines has been a formidable and longstanding …

The oxime ester moiety exists in a large number of bioactive compounds by a wide range of
activities, including antibacterial, antifungal, anti-inflammatory, antioxidant, anti-diabetes and …

The hydrogenation of oximes and oxime ethers is usually hampered by N O bond
cleavage, hence affording amines rather than hydroxylamines. The boron Lewis acid B …

Catalytic reduction of oximes represents a direct efficient approach to synthesize valuable
hydroxylamine derivatives. However this transformation presents significant challenges …

We found that cyclometalated cyclopentadienyl iridium (III) complexes are uniquely efficient
catalysts in homogeneous hydrogenation of oximes to hydroxylamine products. A stable …