Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye

R Böhmer, C Gainaru, R Richert - Physics Reports, 2014 - Elsevier
In 1913 Debye devised a relaxation model for application to the dielectric properties of water
and alcohols. These hydrogen-bonded liquids continue to be studied extensively because …

A novel nanofiltration membrane with [MimAP][Tf2N] ionic liquid for utilization of lithium from brines with high Mg2+/Li+ ratio

H Wu, Y Lin, W Feng, T Liu, L Wang, H Yao… - Journal of Membrane …, 2020 - Elsevier
In order to utilize lithium from brines with high Mg 2+/Li+ ratio, a positively charged
nanofiltration (NF) membrane was prepared by grafting amine-functionalized ionic liquid 1 …

Broadband dielectric spectroscopy—A practical guide

WHH Woodward - Broadband Dielectric Spectroscopy: A Modern …, 2021 - ACS Publications
The purpose of this chapter is to provide a practical overview of broadband dielectric
spectroscopy (BDS) as it applies to the modern analytical chemistry laboratory. The word …

Mechanism of conductivity relaxation in liquid and polymeric electrolytes: Direct link between conductivity and diffusivity

C Gainaru, EW Stacy, V Bocharova… - The Journal of …, 2016 - ACS Publications
Combining broadband impedance spectroscopy, differential scanning calorimetry, and
nuclear magnetic resonance we analyzed charge and mass transport in two polymerized …

Electrochemical stability of low viscosity ion-pair electrolytes: structure and interaction in quaternary ammonium-based ionic liquid containing bis …

SF Ayatollahi, M Bahrami, MH Ghatee - Electrochimica Acta, 2024 - Elsevier
Quaternary ammonium-based ionic liquids (QAIL) consist of an aliphatic cation and possess
characteristic properties different from those of aromatic (like imidazolium) with extensive …

[HTML][HTML] Ion transport and structural dynamics in homologous ammonium and phosphonium-based room temperature ionic liquids

PJ Griffin, AP Holt, K Tsunashima… - The Journal of …, 2015 - pubs.aip.org
Charge transport and structural dynamics in a homologous pair of ammonium and
phosphonium based room temperature ionic liquids (ILs) have been characterized over a …

Molecular dynamics of supercooled ionic liquids studied by light scattering and dielectric spectroscopy

F Pabst, J Gabriel, P Weigl, T Blochowicz - Chemical Physics, 2017 - Elsevier
We investigate molecular dynamics of two supercooled room temperature ionic liquids
(RTILs) above of their glass transition temperature by means of dynamic light scattering and …

Nonhalogenated surface-active ionic liquid as an electrolyte for supercapacitors

P Jain, ON Antzutkin - ACS Applied Energy Materials, 2021 - ACS Publications
We report a nonhalogenated surface-active ionic liquid (SAIL) that consists of the surface-
active anion 2-ethylhexyl sulfate and the tetraoctylammonium cation ([N8, 8, 8, 8][EHS]). We …

Oscillatory shear and high-pressure dielectric study of 5-methyl-3-heptanol

C Gainaru, M Wikarek, S Pawlus, M Paluch… - Colloid and polymer …, 2014 - Springer
Abstract The monohydroxy alcohol 5-methyl-3-heptanol is studied using rheology at ambient
pressure and using dielectric spectroscopy at elevated pressures up to 1.03 GPa. Both …