This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …

This review provides an in-depth analysis of recent advances and strategies employed in
the Pd-catalysed asymmetric allylic alkylation (Pd-AAA) of nucleophilic prochiral …

Covering: up to the end of 2017 Enantioselective Pd-catalyzed allylic alkylations of prochiral
enolates represent a powerful tool for the construction of all-carbon quaternary …

The Stetter reaction is actually a special C− C bond forming reaction through a 1, 4‐addition
reaction in the presence of nucleophilic catalyst. It involves a reaction between aldehydes …

Abstract Synthetically versatile 3, 3‐disubstituted fluorooxindoles exhibiting vicinal chirality
centers were obtained in high yields and with excellent enantio‐, diastereo‐, and …

The first enantioselective total synthesis of (−)-hunterine A is disclosed. Our strategy
employs a catalytic asymmetric desymmetrization of a symmetrical diketone and subsequent …

Many natural products have intriguing medicinal properties that arise from their fascinating
chemical structures. This structural complexity means that the total synthesis of natural …

Covering: up to 2018 Tryptophol (indole-3-ethanol) is a metabolite produced by plants,
bacteria, fungi and sponges. This review reports on the natural occurrence, bioactivity and …