Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

The concept of active site in heterogeneous catalysis

C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …

Low-temperature upcycling of polyolefins into liquid alkanes via tandem cracking-alkylation

W Zhang, S Kim, L Wahl, R Khare, L Hale, J Hu… - Science, 2023 - science.org
Selective upcycling of polyolefin waste has been hampered by the relatively high
temperatures that are required to cleave the carbon-carbon (C–C) bonds at reasonably high …

Solid-state NMR spectroscopy

B Reif, SE Ashbrook, L Emsley, M Hong - Nature Reviews Methods …, 2021 - nature.com
Solid-state nuclear magnetic resonance (NMR) spectroscopy is an atomic-level method to
determine the chemical structure, 3D structure and dynamics of solids and semi-solids. This …

[HTML][HTML] Diamond surface engineering for molecular sensing with nitrogen—vacancy centers

E Janitz, K Herb, LA Völker, WS Huxter… - Journal of Materials …, 2022 - pubs.rsc.org
Quantum sensing using optically addressable atomic-scale defects, such as the nitrogen-
vacancy (NV) center in diamond, provides new opportunities for sensitive and highly …

Carbocation chemistry confined in zeolites: spectroscopic and theoretical characterizations

W Chen, X Yi, Z Liu, X Tang, A Zheng - Chemical Society Reviews, 2022 - pubs.rsc.org
Acid-catalyzed reactions inside zeolites are one type of broadly applied industrial reactions,
where carbocations are the most common intermediates of these reaction processes …

Recent Advances of Solid‐State NMR Spectroscopy for Microporous Materials

S Li, O Lafon, W Wang, Q Wang, X Wang… - Advanced …, 2020 - Wiley Online Library
Microporous materials have attracted a rapid growth of research interest in materials science
and the multidisciplinary area because of their wide applications in catalysis, separation, ion …

Unraveling Sodium-Ion Dynamics in Honeycomb-Layered Na2MgxZn2–xTeO6 Solid Electrolytes with Solid-State NMR

D Sarkar, A Bhattacharya, J Meyer… - Journal of the …, 2023 - ACS Publications
All-solid-state sodium-ion batteries (SIBs) have the potential to offer large-scale, safe, cost-
effective, and sustainable energy storage solutions by supplementing the industry-leading …

The superior hydrothermal stability of Pd/SSZ-39 in low temperature passive NOx adsorption (PNA) and methane combustion

K Khivantsev, NR Jaegers, L Kovarik, M Wang… - Applied Catalysis B …, 2021 - Elsevier
Abstract Uniform SSZ-39 (Si/Al ratio∼ 12) crystals with an average size of about one micron
were synthesized and used to support Pd (0.7–3 wt%) for PNA. The as-synthesized …

Studying, promoting, exploiting, and predicting catalyst dynamics: the next frontier in heterogeneous catalysis

S Chavez, B Werghi… - The Journal of …, 2023 - ACS Publications
Developing heterogeneous catalysts involves continuous efforts in understanding and
designing active sites with improved performance for various applications. In recent years …