Advances in membrane-based chiral separation
Chiral separation is essential in discovering bioactive substances because the enantiomer
of chiral drugs usually exhibits different or even opposite biological activity and toxicity. As a …
of chiral drugs usually exhibits different or even opposite biological activity and toxicity. As a …
Structure control of polysaccharide derivatives for efficient separation of enantiomers by chromatography
T Ikai, Y Okamoto - Chemical Reviews, 2009 - ACS Publications
Chirality is a ubiquitous feature in living systems. Today, it is widely recognized that many
biologically interesting compounds, such as drugs, agrochemicals, food additives, and …
biologically interesting compounds, such as drugs, agrochemicals, food additives, and …
Engineering chiral porous metal-organic frameworks for enantioselective adsorption and separation
The separation of racemic molecules is of substantial significance not only for basic science
but also for technical applications, such as fine chemicals and drug development. Here we …
but also for technical applications, such as fine chemicals and drug development. Here we …
The chiral nano-world: chiroptically active quantum nanostructures
Chirality is one of the key factors in molecular recognition, therefore the development of new
chiral nanoparticles is of great interest to many fields of scientific endeavour including …
chiral nanoparticles is of great interest to many fields of scientific endeavour including …
Identifying a hidden conglomerate chiral pool in the CSD
MP Walsh, JA Barclay, CS Begg, J Xuan, NT Johnson… - JACS Au, 2022 - ACS Publications
Conglomerate crystallization is the spontaneous generation of individually enantioenriched
crystals from a nonenantioenriched material. This behavior is responsible for spontaneous …
crystals from a nonenantioenriched material. This behavior is responsible for spontaneous …
Enhanced direct crystallization resolution of racemates mediated in chiral ionic liquid cosolvent mixtures: experimental, statistical, and QM simulation studies
X Qin, Y Xu, B Lou, C Liu, L Zhang, X Liu… - Crystal Growth & …, 2023 - ACS Publications
Four chiral ionic liquids (CILs) of 1-hexyl-3-methylimidazolium-l-2-aminobutyrate ([Hmim][l-2-
AbA]), 1-hexyl-3-methylimidazolium-d-2-aminobutyrate ([Hmim][d-2-AbA]), di-1-hexyl-3 …
AbA]), 1-hexyl-3-methylimidazolium-d-2-aminobutyrate ([Hmim][d-2-AbA]), di-1-hexyl-3 …
Developments in the catalytic asymmetric synthesis of agrochemicals and their synthetic importance
SK Sharma, ASR Paniraj… - Journal of Agricultural and …, 2021 - ACS Publications
Catalytic asymmetric synthesis has become an essential tool for the enantioselective
synthesis of pharmaceuticals, natural products, and agrochemicals (mainly fungicides …
synthesis of pharmaceuticals, natural products, and agrochemicals (mainly fungicides …
Effect of stereogenic centers on the self-sorting, depolymerization, and atropisomerization kinetics of porphyrin-based aggregates
F Helmich, MMJ Smulders, CC Lee… - Journal of the …, 2011 - ACS Publications
We present our results on the mixing of different porphyrin molecules in supramolecular
assemblies. Herein, chiral amplification experiments reveal the subtle role of the structural …
assemblies. Herein, chiral amplification experiments reveal the subtle role of the structural …
Effect of additives on preferential crystallization for the chiral resolution of citrulline: experimental, statistical, and molecular dynamics simulation studies
L Zhang, Y Xu, B Lou, X Qin, L Zhang, X Liu… - Crystal Growth & …, 2022 - ACS Publications
The molar fraction solubilities of l-, d-, and dl-citrulline were first determined in aqueous
solutions with different concentrations of (R)-1, 3-butanediol from 283.15 to 328.15 K under …
solutions with different concentrations of (R)-1, 3-butanediol from 283.15 to 328.15 K under …
Completely chiral optical force for enantioseparation
Fast and reliable separation of enantiomers of chiral nanoparticles requires elimination of all
the forces that are independent of the nanoparticle handedness and creation of a sufficiently …
the forces that are independent of the nanoparticle handedness and creation of a sufficiently …