The multicomponent reactions of quinoxalin‐2 (1H)‐ones has attracted considerable interest
due to their significant biological and chemical activities. The very recent advances (from …

Fluorinated alkyl iodides serve as a convenient and inexpensive source of fluoroalkyl
radicals that can readily undergo addition to the C− C unsaturated bonds of alkynes and …

Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …

Abstract In recent years, numerous 1, 2-R shift (R= aliphatic or aryl) based on
tetracoordinate boron species have been well investigated. In the contrary, the …

Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …

Tri (t-butyl) phosphine and terminal alkynes undergo 1, 2-phosphorus-migrative [3+ 2]
cycloaddition in the presence of a proton source under photocatalytic conditions. The …

Bis (boronic) esters can be readily synthesized from alkylBpin precursors. Selective
transformations of these compounds hold the potential for late‐stage functionalization of the …

Although highly appealing for rapid access of molecular complexity, multi‐functionalization
of alkenes that allows incorporation of more than two functional groups remains a prominent …

In this paper, we present the synthetic potential of diarylmethylium tetrafluoroborates as
catalysts for the visible light promoted hydrosulfonylation of unactivated alkenes. For the first …

Herein, we report an intermolecular, radical 1, 2, 3-tricarbofunctionalization of α-vinyl-β-
ketoesters to achieve the goal of building molecular complexity via the one-pot …