A Spontaneously Electrical State of Matter
Conspectus Molecular deposition on solid surfaces forms crystalline or amorphous/glassy
thin solid films. Intermolecular interactions govern the packing and dynamics of these films …
thin solid films. Intermolecular interactions govern the packing and dynamics of these films …
Hydrogen bond networks of ammonia clusters: What we know and what we don't know
A Malloum, J Conradie - Journal of Molecular Liquids, 2021 - Elsevier
Understanding the behaviour of liquid ammonia is subjected to understanding the hydrogen
bond networks in ammonia clusters as well as their interactions. In comparison to water …
bond networks in ammonia clusters as well as their interactions. In comparison to water …
Switch chemistry at cryogenic conditions: quantum tunnelling under electric fields
O Kirshenboim, A Frenklah, S Kozuch - Chemical Science, 2021 - pubs.rsc.org
While the influence of intramolecular electric fields is a known feature in enzymes, the use of
oriented external electric fields (EEF) to enhance or inhibit molecular reactivity is a …
oriented external electric fields (EEF) to enhance or inhibit molecular reactivity is a …
Quantum Tunneling in Reactions Modulated by External Electric Fields: Reactivity and Selectivity
Quantum tunneling and external electric fields (EEFs) can promote some reactions.
However, the synergetic effect of an EEF on a tunneling-involving reaction and its …
However, the synergetic effect of an EEF on a tunneling-involving reaction and its …
Hopping conductance in molecular wires exhibits a large heavy-atom kinetic isotope effect
QV Nguyen, CD Frisbie - Journal of the American Chemical …, 2021 - ACS Publications
We report a large kinetic isotope effect (KIE) for intramolecular charge transport in π-
conjugated oligophenyleneimine (OPI) molecules connected to Au electrodes. 13C and 15N …
conjugated oligophenyleneimine (OPI) molecules connected to Au electrodes. 13C and 15N …
Recent Progress in the Manipulation of Molecules with DC Electric Fields
Conspectus The structure and reactivity of a molecule in the condensed phase are governed
by its intermolecular interactions with the surrounding environment. The multipole expansion …
by its intermolecular interactions with the surrounding environment. The multipole expansion …
Fluxionality by quantum tunnelling: nonclassical 21-homododecahedryl cation rearrangement re-revisited
The 21-homododecahedryl cation is a unique system in terms of its complete fluxionality
based on two different rearrangements. In this work, we report the quantum tunneling effects …
based on two different rearrangements. In this work, we report the quantum tunneling effects …
Solid Ammonia Charging by Low-Energy Electrons
R Sagi, M Akerman, S Ramakrishnan… - The Journal of Physical …, 2021 - ACS Publications
The interaction of condensed matter with low-energy electrons is relevant to a broad range
of research fields as this interaction is directly associated with radiation chemistry. When …
of research fields as this interaction is directly associated with radiation chemistry. When …
An Introduction to Laser-field Effects on Chemical Reactivity
CF Matta, AD Bandrauk - 2021 - books.rsc.org
the wavelength of the radiation is taken as infinite. The fields considered here are
homogenous and, hence, there will be no terms in the energy expansion that are functions …
homogenous and, hence, there will be no terms in the energy expansion that are functions …
Manipulation of Molecules by Combined Permanent and Induced Dipole Forces
B Friedrich - 2021 - books.rsc.org
All molecules possess a handle that can be used to manipulate their rotation and/or
translation. This metaphorical handle is the molecular electric dipole moment, either …
translation. This metaphorical handle is the molecular electric dipole moment, either …