Tautomeric equilibria in relation to pi-electron delocalization

ED Raczyńska, W Kosińska, B Ośmiałowski… - Chemical …, 2005 - ACS Publications
Tautomerism, a particular case of isomerism, plays an important role in modern organic
chemistry, biochemistry, medicinal chemistry, pharmacology, molecular biology, and life …

Synthesis and photophysical characterization of a Schiff base as anion sensor

YM Hijji, B Barare, AP Kennedy, R Butcher - Sensors and Actuators B …, 2009 - Elsevier
A colorimetric anion sensor was developed using the Schiff base formed from the
condensation of salicylaldehyde and 2-amino-4-nitrophenol under microwave irradiation …

Intramolecular hydrogen bonding and tautomerism in Schiff bases: Part VI. Syntheses and structural investigation of salicylaldimine and naphthaldimine derivatives

S Bilge, Z Kilic, Z Hayvali, T Hökelek… - Journal of Chemical …, 2009 - Springer
Abstract Salicyclaldimines (5–9) and naphthaldimines (10–13) derived from condensation
reactions of N 2 O 2 donor type bifunctional aminopodands (1–4),[(H 2 NPhO) 2 R, where …

Imine or Enamine? Insights and Predictive Guidelines from the Electronic Effect of Substituents in H-Bonded Salicylimines

RF Martínez, E Matamoros, P Cintas… - The Journal of Organic …, 2020 - ACS Publications
Imine and enamine bonds decorate the skeleton of numerous reagents, catalysts, and
organic materials. However, it is difficult to isolate at will a single tautomer, as dynamic …

An intermediate structure trapped in solid-state tautomerization process of (E)-4-[(4-chlorophenylimino) methyl] benzene-1, 2, 3-triol

H Karabıyık, N Ocak-Iskeleli, H Petek… - Journal of Molecular …, 2008 - Elsevier
An intermediate structure between the benzenoid and cis-quinoid form of the title compound
was trapped in solid-state tautomerization with the aid of OH⋯ O type intermolecular H …

Zwitterionic (E)-2-hydroxy-6-[(o-tolyliminio) methyl] phenolate 0.07-hydrate

E Temel, Ç Albayrak, O Büyükgüngör… - … Section E: Structure …, 2006 - journals.iucr.org
The title compound, C14H13NO2· 0.07 H2O, crystallizes in a zwitterionic form. The dihedral
angle between the aromatic rings is 29.23 (4)°. An N—H⋯ O hydrogen bond generates an S …

4-(2-Hydroxyphenyliminomethylene) phenol

CC Ersanlı, Ç Albayrak, M Odabaşoğlu… - … Section E: Structure …, 2004 - journals.iucr.org
The asymmetric unit of the title compound, C13H11NO2, consists of two crystallographically
independent molecules which are essentially planar and are approximately orthogonal to …

Crystallographic and Conformational Analysis of [(Z)-2-ethoxy-6-[(2-hydroxyphenylamino)methylene]cyclohexa-2,4-dienone]

H Petek, Ç Albayrak, M Odabaşoğlu, İ Şenel… - Journal of Chemical …, 2008 - Springer
The single crystal X-ray diffraction analysis of the title compound, C 15 H 15 NO 3, shows
that the structure is adopted to its NH tautomeric form and crystallizes in the orthorhombic …

Chiral N-Acyloxazolidines:  Synthesis, Structure, and Mechanistic Insights

M Ávalos, R Babiano, P Cintas… - The Journal of …, 2008 - ACS Publications
A series of chiral imines derived from 1-amino-1-deoxyalditols such as d-glucamine, a rather
unexplored raw material from the chiral pool, have been serendipitiously transformed into a …

Structural and aromatic aspects for tautomerism of (Z)-6-((4-bromophenylamino)methylene)-2,3-dihydroxycyclohexa-2,4-dienone

H Karabıyık, H Petek, NO Iskeleli, Ç Albayrak - Structural Chemistry, 2009 - Springer
The molecular and crystal structure of (Z)-6-((4-bromophenylamino) methylene)-2, 3-
dihydroxycyclohexa-2, 4-dienone were determined by single crystal X-ray diffraction and …