Electrode–electrolyte interfaces play a decisive role in electrochemical charge accumulation
and transfer processes. Theoretical modelling of these interfaces is critical to decipher the …

Understanding how applied potentials and electrolyte solution conditions affect interfacial
proton (charge) transfers at electrode surfaces is critical for electrochemical technologies …

An abnormal optical absorption at about 780 and 980 nm was observed for Au25
nanoclusters (NCs) protected by negatively charged thiolate ligands collocating with …

While thiolate-protected Au nanoclusters (NCs) have drawn considerable interest in various
fields, their poor stability in aqueous solution remains a major hurdle for practical …

It has been a long challenge to understand the equilibrium and the dynamic phenomena (eg
chemical reactions) at the electrode/electrolyte interface in a unified theoretical framework …

4-mercaptobenzonitrile (MBN) in self-assembled monolayers (SAMs) on Au and Ag
electrodes was studied by surface enhanced infrared absorption and Raman spectroscopy …

Deciphering which parameters control the immobilization of enzymes on solid supports is
essential for the development of biotechnological devices such as biosensors, bioreactors …

We have designed and synthesized a helical cysteamine-terminated oligourea foldamer
composed of ten urea residues featuring side carboxyl and amine groups. The carboxyl …

The immersion method was used to measure the potential of zero free charge (E pzfc) of a
bare Au (111) electrode and the electrode modified by self-assembled monolayers (SAMs) …

By combining a description of the potential profile at electrodes coated with acid thiol
monolayers with a quadratic relationship between activation energy and electrode potential …