Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating
nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be …

A key goal of organic chemistry is to develop new principles for the control of reactions,
which can be used to create promising materials demanded in all fields of scientific research …

Abstract Photochemistry of 3-chloro-1, 2-benzisoxazole 1 in N 2 and Ar matrices at 10 K
leads to N-chloro-ketenimine 3 and 2-cyanophenyl-hypochlorite 4. The reaction kinetics and …

The photolysis of tetrazoles has undergone extensive research. However, there are still
some problems to be solved in terms of mechanistic understanding and reactivity analyses …

Photochromism of spiropyrans has attracted much attention due to its potential in many light-
controlled system applications. However, several fundamental aspects regarding the …

The monomers of 1, 3-benzoxazole isolated in a cryogenic argon matrix were characterized
by infrared spectroscopy. The photochemistry of matrix-isolated 1, 3-benzoxazole, induced …

Both photolysis and flash vacuum pyrolysis (FVP) of tetrazoles (1/5) are known to generate
nitrile imines (13, 19, and 38), which rearrange to 1 H-diazirines, imidoylnitrenes, and …

Photolysis of 1-and 5-aryltetrazoles at 5–10 K using a 266 nm laser immediately generates
their triplet excited states, which are characterized by their electron spin resonance (ESR) …

The structures, energies, and rearrangements of imidoylnitrenes H–C ( NH)–N, H2N–C (
NH)–N, Ph–C ( NH)–N, H–C ( NPh)–N, and MeO–C ( NCN)–N (10a–e) are investigated …

The intriguing ability of C-phenyl-nitrilimine to co-exist as allenic and propargylic bond-shift
isomers motivated us to investigate how substituents in the phenyl ring influence this …