Cooperative Bifurcated Chalcogen Bonding and Hydrogen Bonding as Stereocontrolling Elements for Selective Strain-Release Septanosylation

W Ma, JL Kirchhoff, C Strohmann… - Journal of the …, 2023 - ACS Publications
The exploitation of noncovalent interactions (NCIs) is emerging as a vital handle in tackling
broad stereoselectivity challenges in synthesis. In particular, there has been significant …

Biochemical analyses of bioactive extracts from plants native to Lampedusa, Sicily minor island

R Di Lecce, N Mérindol, MG Pérez, V Karimzadegan… - Plants, 2022 - mdpi.com
Major threats to the human lifespan include cancer, infectious diseases, diabetes, mental
degenerative conditions and also reduced agricultural productivity due to climate changes …

Synthesis of a Diacetonide-Protected, Mannose-Based Oxepine: Configurational Control of Anomeric Acetate Activation

B Pero, MW Peczuh - The Journal of organic chemistry, 2022 - ACS Publications
Carbohydrate-based oxepines are seven-membered-ring oxacycles containing an enol
ether moiety. These compounds have been used as intermediates in the preparation of …

Indolyl septanoside synthesis for in vivo screening of bacterial septanoside hydrolases

AR Pote, S Pascual, A Planas, MW Peczuh - International Journal of …, 2021 - mdpi.com
Building-up and breaking-down of carbohydrates are processes common to all forms of life.
Glycoside hydrolases are a broad class of enzymes that play a central role in the cleavage …

Synthesis of ring-expanded homologs of 3-amino pyranosides

C Bosko, R Vannam, MW Peczuh - Tetrahedron Letters, 2022 - Elsevier
Amino pyranosides are an important component of natural products like vancomycin and
erythromycin. The amine moiety mediates interactions with the biological targets of the …

Recent advances in the radiation chemistry of destructured starch and other glucans as model compounds

D Khandal, S Fatahiyah Mohamad, X Coqueret - 2021 - books.rsc.org
This chapter overviews the influence of radiation processing applied to thermoplastic starch
and some other glucans in blends prepared with various types of plasticizers and additives …

Sonogashira cross-coupling on carbohydrate templates

RFN Silva, S Silva, P Rollin, AP Rauter - 2021 - books.rsc.org
Recently introduced in glycochemistry, the Sonogashira cross-coupling reaction has shown
a promising potential in connecting widely varied structural units with carbohydrate …